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Sodium diethyldithiocarbamate
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Name

Sodium diethyldithiocarbamate

 EINECS 205-710-6
CAS No. 148-18-5 Density 1.086 g/cm3
PSA 60.63000 LogP 1.81060
Solubility water: >=10 g/100 mL at 14 °C Melting Point 95 °C
Formula C5H10NNaS2 Boiling Point 176.4 °C at 760 mmHg
Molecular Weight 171.263 Flash Point 60.5 °C
Transport Information N/A Appearance Odorless white or slightly brown or slightly pink crystals
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 148-18-5 (Sodium diethyldithiocarbamate) Hazard Symbols N/A
Synonyms

Sodium N,N-diethyldithiocarbamate;Carbamic acid, diethyldithio-, sodium salt;DEDC;Soxinol ESL;Diethyldithiocarbamic acid, sodium;Usaf ek-2596;DEDK;Ditiocarb sodium;Diethyldithiocarbamic acid, sodium salt;Thiocarb;GS 694A;NCI-C02835;DTC;DDC;

Article Data 23

Sodium diethyldithiocarbamate Synthetic route

75-15-0

carbon disulfide

109-89-7

diethylamine

148-18-5

sodium N,N-diethyldithiocarbamate

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water cooling;90%
With sodium hydroxide In ethanol at 20 - 40℃;73%
With sodium hydroxide In water at 20℃; for 1h; Cooling with ice;69%
97-77-8

disulfiram

140-90-9

sodium O-ethyl dithiocarbonate

A

148-18-5

sodium N,N-diethyldithiocarbamate

B

327989-09-3

C8H15NOS4

Conditions
ConditionsYield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Rate constant; Equilibrium constant; μ 0.2 mol/l;
97-77-8

disulfiram

4092-82-4

sodium N,N'-diisopropyldithiocarbamate

A

148-18-5

sodium N,N-diethyldithiocarbamate

B

C12H24N2S4

Conditions
ConditionsYield
With sodium nitrate; potassium hexacyanoferrate(III) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;
140-90-9

sodium O-ethyl dithiocarbonate

327989-09-3

C8H15NOS4

A

502-55-6

bis-ethoxythiocarbonyldisulfane

B

148-18-5

sodium N,N-diethyldithiocarbamate

Conditions
ConditionsYield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Rate constant; Equilibrium constant; μ 0.2 mol/l;
4092-82-4

sodium N,N'-diisopropyldithiocarbamate

C12H24N2S4

A

4136-91-8

tetraisopropylothiuram disulphide

B

148-18-5

sodium N,N-diethyldithiocarbamate

Conditions
ConditionsYield
With sodium nitrate; potassium hexacyanoferrate(III) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;
138523-63-4

Tributyltin diethyldithiocarbamate

148-18-5

sodium N,N-diethyldithiocarbamate

Conditions
ConditionsYield
With sodium hydrogensulfide In methanol at 4℃;
80-05-7

BPA

concentrated NaOH

concentrated NaOH

N-(hydroxyethyl)-ethylenediamine

112-34-5

Diethylene glycol monobutyl ether

120-32-1

chlorophene

148-18-5

sodium N,N-diethyldithiocarbamate

...Expand
148-18-5

sodium N,N-diethyldithiocarbamate

5'-I-d(TTT)-CPG resin

5'-I-d(TTT)-CPG resin

C35H49N7O18P2S2

Conditions
ConditionsYield
Stage #1: sodium N,N-diethyldithiocarbamate; 5'-I-d(TTT)-CPG resin In N,N-dimethyl-formamide at 20℃; for 0.0333333h;
Stage #2: With ammonium hydroxide at 60℃; for 17h;		100%

[Re(S3CPh)2(S2CPh)]

148-18-5

sodium N,N-diethyldithiocarbamate

bis(trithioperoxybenzoato)-(diethyldithiocarbamato)rhenium (III)

Conditions
ConditionsYield
In methanol; dichloromethane at 20℃; for 1h;100%
148-18-5

sodium N,N-diethyldithiocarbamate

572-09-8

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

S-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl) N,N-diethyldithiocarbamate

Conditions
ConditionsYield
In acetone for 1h; Reflux;99%
In acetonitrile at 25℃; for 1h;63%

Sodium diethyldithiocarbamate Chemical Properties

IUPAC Name: sodium N,N-diethylcarbamodithioate
Following is the structure of Sodium diethyldithiocarbamate (CAS NO.148-18-5):
                             
Molecular formula: C5H10NNaS2 
Molecular Weight: 171.26
EINECS: 205-710-6
Melting point: 95°C 
Flash Point: 60.5 °C 
Index of Refraction: 1.555 
Molar Refractivity: 44.12 cm3
Molar Volume: 137.3 cm3
Density: 1.086 g/cm3
Surface Tension: 44.6 dyne/cm
Boiling Point: 176.4 °C at 760 mmHg
Enthalpy of Vaporization: 41.27 kJ/mol 
Vapour Pressure: 1.1 mmHg at 25 °C
Water Solubility of Sodium diethyldithiocarbamate (CAS NO.148-18-5): >=10 g/100 mL at 14 °C
Product Categories of Sodium diethyldithiocarbamate (CAS NO.148-18-5): Pharmaceutical Intermediates; Aliphatics  
Canonical SMILES: CCN(CC)C(=S)[S-].[Na+]
InChI: InChI=1S/C5H11NS2.Na/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1
InChIKey: IOEJYZSZYUROLN-UHFFFAOYSA-M

Sodium diethyldithiocarbamate Uses

 Sodium diethyldithiocarbamate (CAS NO.148-18-5) can be used as a pesticide.

Sodium diethyldithiocarbamate Toxicity Data With Reference

1.    

oms-omi 100 µmol/L

     BBACAQ    Biochimica et Biophysica Acta. 519 (1978),65.
2.    

dnd-hmn:hla 100 µmol/L

     BBACAQ    Biochimica et Biophysica Acta. 519 (1978),65.
3.    

cyt-rat-orl 5200 mg/kg

     MUREAV    Mutation Research. 53 (1978),212.
4.    

dni-ckn:emb 4 µmol/L

     BBACAQ    Biochimica et Biophysica Acta. 519 (1978),65.
5.    

oms-ckn:emb 40 µmol/L

     BBACAQ    Biochimica et Biophysica Acta. 519 (1978),65.
6.    

orl-rat LD50:1500 mg/kg

     DRFUD4    Drugs of the Future. 6 (1981),225.
7.    

ipr-rat LD50:1250 mg/kg

     DRFUD4    Drugs of the Future. 6 (1981),225.
8.    

orl-mus LD50:1500 mg/kg

     DRFUD4    Drugs of the Future. 6 (1981),225.
9.    

ipr-mus LD50:1302 mg/kg

     DRFUD4    Drugs of the Future. 6 (1981),225.
10.    

scu-rbt LD50:500 mg/kg

     APTOA6    Acta Pharmacologica et Toxicologica. 8 (1952),329.

Sodium diethyldithiocarbamate Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 12 ,1976,p. 217.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-172 ,1979. . Reported in EPA TSCA Inventory.

Sodium diethyldithiocarbamate Safety Profile

 Moderately is toxic by ingestion, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Questionable carcinogen with experimental neoplastigenic and teratogenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, SOx, and Na2O. See also CARBAMATES.

Sodium diethyldithiocarbamate Standards and Recommendations

DFG MAK: 2 mg/m3

Sodium diethyldithiocarbamate Specification

 Sodium diethyldithiocarbamate , its cas register number is 148-18-5. It also can be called Diethyldithiocarbamic acid sodium salt ; N,N-Diethyldithiocarbamic acid, sodium salt ; and Sodium N,N-diethyldithiocarbamate . Its classification code are Agricultural Chemical; Antidote for nickel and cadmium poisoning; Fungicide, bactericide, wood preservative; Mutation data ; Reproductive Effect and Tumor data.

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