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Sodium phosphide

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Name

Sodium phosphide

EINECS N/A
CAS No. 12058-85-4 Density g/cm3
PSA 13.59000 LogP 0.05810
Solubility decomposes in H2O, evolving PH3 [CRC10] [HAW93] Melting Point stable up to 650℃ [KIR82]
Formula Na3P Boiling Point °Cat760mmHg
Molecular Weight 99.9431 Flash Point °C
Transport Information N/A Appearance N/A
Safety Flammable when exposed to heat or flame. Reacts violently with water to yield phosphine. When heated to decomposition it emits toxic fumes of POx and Na2O. See also PHOSPHIDES. Risk Codes N/A
Molecular Structure Molecular Structure of 12058-85-4 (SODIUM PHOSPHIDE) Hazard Symbols Dangerous fire risk, reacts with water and acids to form phosphine.
Synonyms

Trisodiophosphine;Trisodium phosphide

Article Data 31

Sodium phosphide Chemical Properties

Molecular Structure of Sodium phosphide (CAS NO.12058-85-4):


IUPAC: Disodiophosphanylsodium
Molecular Formula:Na3P
Molecular Weight:99.94
EINECS:235-031-0
SMILES:[Na]P([Na])[Na]
InChI:InChI=1/3Na.P/rNa3P/c1-4(2)3 
InChIKey:WROHAQZYIUQHNL-NNSBWOSJAJ
Polarizability:10-24cm3

Sodium phosphide Consensus Reports

Reported in EPA TSCA Inventory.

Sodium phosphide Safety Profile

Flammable when exposed to heat or flame. Reacts violently with water to yield phosphine. When heated to decomposition it emits toxic fumes of POx and Na2O. See also PHOSPHIDES.

Safety Information of Sodium phosphide (CAS NO.12058-85-4):
RIDADR:1432
HazardClass:4.3
PackingGroup:I

Sodium phosphide Standards and Recommendations

DOT Classification:  4.3; Label: Dangerous When Wet, Poison

Sodium phosphide Specification

 Sodium phosphide with cas registry number of 12058-85-4 is also known as Sodium phosphide ; Trisodium phosphide . It is a source of the highly reactive phosphide with the appearance of black solid . It can not be soluble in water and liquid CO2. Sodium phosphide with cas registry number of 12058-85-4 is employed commercially as a catalyst in conjunction with zinc phosphide and aluminium phosphide for polymer production. Sodium phosphide is highly dangerous releasing toxic phosphine upon hydrolysis. It is easy to react with water and acids to form phosphine. Na3P has been forbidden to transport on passenger aircraft, cargo only aircraft, and trains because of the potential fire and toxic hazards .

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