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Sodium selenide

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Name

Sodium selenide

EINECS N/A
CAS No. 1313-85-5 Density g/cm3
PSA 0.00000 LogP -0.38080
Solubility N/A Melting Point >875°C
Formula Na2Se Boiling Point °Cat760mmHg
Molecular Weight 124.94 Flash Point °C
Transport Information N/A Appearance N/A
Safety Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of Se and Na2O. See also SELENIUM COMPOUNDS. Risk Codes R23/25; R33; R50/53
Molecular Structure Molecular Structure of 1313-85-5 (Sodium selenide) Hazard Symbols N/A
Synonyms

Disodiummonoselenide; Disodium selenide; Sodium selenide

Article Data 1

Sodium selenide Synthetic route

7782-49-2

selenium

16940-66-2

sodium tetrahydroborate

1313-85-5

sodium selenide

Conditions
ConditionsYield
In water Inert atmosphere; Schlenk technique;
1313-85-5

sodium selenide

70335-45-4

2,4,6-trimethylphenyl diazonium chloride

142073-25-4

bis(2,4,6-trimethylphenyl) selenide

Conditions
ConditionsYield
In water at 40℃; for 3h; Inert atmosphere; Schlenk technique;60%

Sodium selenide Chemical Properties

Molecular Structure of Sodium selenide (CAS NO.1313-85-5):


IUPAC: Sodioselanylsodium
EINECS:215-212-0
Molecular Formula:Na2Se
Molecular Weight:124.94
Density:2.625 g/mL at 25oC(lit.)
Melting Point:>875oC
Sensitive:Moisture
Merck:14,8672
InChI:InChI=1/2Na.Se/rNa2Se/c1-3-2
InChIKey:PNCGYTHKTDMKME-SJGDNHCQAR 

Sodium selenide Toxicity Data With Reference

1.    

sce-ham:lng 2 mg/L

    CALEDQ    Cancer Letters (Shannon, Ireland). 18 (1983),109.
2.    

ipr-mus LD50:4 mg/kg

    COREAF    Comptes Rendus Hebdomadaires des Seances de lAcademie des Sciences. 257 (1963),791.

Sodium selenide Consensus Reports

Selenium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Sodium selenide Safety Profile

Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of Se and Na2O. See also SELENIUM COMPOUNDS.

Safety Information of Sodium selenide (CAS NO.1313-85-5):
Risk Statements: 23/25-33-50/53
R23/25:Toxic by inhalation and if swallowed.
R33:Danger of cumulative effects.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 28-45-60-61
S28:After contact with skin, wash immediately with plenty of soap-suds.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN3134
HazardClass: 4.3
PackingGroup: II

Sodium selenide Standards and Recommendations

OSHA PEL: TWA 0.2 mg(Se)/m3
ACGIH TLV: TWA 0.2 mg(Se)/m3
DFG MAK: 0.1 mg(Se)/m3

Sodium selenide Specification

 Sodium selenide with cas registry number of 1313-85-5 is also known as Disodium monoselenide ; Sodium selenide ; Disodium selenide ; Sodium selenide . It is a compound with the appearance of white to red cubic crystals. It can be souble in water and it should be stored in a tightly closed container when not in use and stored in a cool, dry place. Sodium selenide can be obtained by the reduction of CH2ONaHSO22H2O . Sodium selenide with cas registry number of 1313-85-5 is used as an intermediate .

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