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Triforine

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Name

Triforine

EINECS N/A
CAS No. 26644-46-2 Density 1.59g/cm3
PSA 64.68000 LogP 3.41800
Solubility 9 mg l-1 (20 °C) Melting Point 155oC (decomposes)
Formula C10H14 Cl6 N4 O2 Boiling Point 561.5oC at 760 mmHg
Molecular Weight 434.965 Flash Point 293.4oC
Transport Information N/A Appearance N/A
Safety Low toxicity by ingestion, inhalation, and skin contact. Human systemic effects: change in taste function. When heated to decomposition emits toxic fumes of NOx and Cl. Risk Codes 52/53-20
Molecular Structure Molecular Structure of 26644-46-2 (TRIFORINE) Hazard Symbols Low toxicity by ingestion, inhalation, and skin contact. Human systemic effects.
Synonyms

1,4-Bis(1-formamido-2,2,2-trichloroethyl)piperazine;Asepta Funginex; Biformylchlorazin; CA 70203; CELA 50; CELA-W 524; Funginex;N,N'-Bis(1-formamido-2,2,2-trichloroethyl)piperazine; NSC 263493; Saprol;Triforin; Triforine; W 524

Article Data 12

Triforine Chemical Properties

IUPAC Name: N-[2,2,2-trichloro-1-[4-(2,2,2-trichloro-1-formamidoethyl)piperazin-1-yl]ethyl]Formamide (26644-46-2)
Synonyms: Saprol ; Saprol(r) ; N,N'-[piperazine-1,4-diylbis(trichloromethyl)methylene]-diformamide ; Piperazin-1,4-diyl-bis-[1-(2,2,2-trichloroethyl)formamide] ; Triforin ; Triforine ; 1,4-bis(1-formamido-2,2,2-trichloroethyl)-Piperazin ; 1,4-bis(1-formamido-2,2,2-trichloroethyl)piperazine
Product Categories: Amide structureAlphabetic;Fungicides;Pesticides;TP - TZ;Alpha sort;Amide structurePesticides&Metabolites;Q-ZAlphabetic
CAS: 26644-46-2
Molecular Formula:C10H14Cl6N4O2
Molecular Weight: 434.96
EINECS: 247-872-0
Molecular Structure:
Mol File: 26644-46-2.mol
Surface Tension: 56.5 dyne/cm 
Density: 1.59 g/cm
Flash Point: 293.4 °C 
Enthalpy of Vaporization: 84.43 kJ/mol 
Boiling Point: 561.5 °C at 760 mmHg 
Vapour Pressure: 1.23E-12 mmHg at 25°C 
storage temp:  0-6°C
Merck : 13,9762
Appearance: Triforine (26644-46-2) is colorless crystals and non corrosive.

Triforine Uses

Triforine (26644-46-2)  is used as a fungicide,Is mainly used for prevention and treatment of vegetables, fruit and cereals powdery mildew and rust. which can also be used  in the prevention and treatment of disease of stored fruits.

Triforine Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LD50 oral > 2gm/kg (2000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A413, Pg. 1983,
man TDLo oral 180uL/kg (0.18mL/kg) SENSE ORGANS AND SPECIAL SENSES: CHANGE IN FUNCTION: TASTE American Journal of Emergency Medicine. Vol. 4, Pg. 554, 1986.
mouse LD50 oral > 6gm/kg (6000mg/kg)   Pesticide Manual. Vol. 9, Pg. 853, 1991.
quail LD50 oral > 5gm/kg (5000mg/kg)   Pesticide Manual. Vol. 9, Pg. 853, 1991.
rabbit LD50 skin > 10gm/kg (10000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A413, Pg. 1983,
rat LC50 inhalation > 4500mg/m3/1H (4500mg/m3)   Pesticide Manual. Vol. 9, Pg. 853, 1991.
rat LD50 intraperitoneal > 4gm/kg (4000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A413, Pg. 1983,
rat LD50 oral 6gm/kg (6000mg/kg)   "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 4, Pg. 81, 1976/1977.
rat LD50 skin > 10gm/kg (10000mg/kg)   Pesticide Manual. Vol. 9, Pg. 853, 1991.

Triforine Safety Profile

Risk Statements  52/53
52/53: Triforine (26644-46-2) is harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment  
Safety Statements  61
61:  Avoid release to the environment. Refer to special instructions safety data sheet 
RTECS  TK9200000 

Triforine Specification

1.Category: Pesticides
2.Toxicity classification: low toxicity
3.Acute toxicity: Oral - rat LD50: 6000 mg / kg; Oral - Mouse LD50: 6000 mg / kg
4.Flammable hazardous characteristics: burning of toxic chloride and nitrogen oxide gases
5.Storage features: Treasury ventilated low-temperature drying; separate from food  raw materials in storage and transportation
6.Fire-extinguishing agent: dry powder, foam, sand.

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