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10049-06-6

Basic Information
CAS No.: 10049-06-6
Name: TITANIUM(II) CHLORIDE
Article Data: 46
Molecular Structure:
Molecular Structure of 10049-06-6 (TITANIUM(II) CHLORIDE)
Formula: Cl2Ti
Molecular Weight: 118.786
Synonyms: Dichlorotitanium;Titanium dichloride; Titanium(II) chloride
EINECS: 233-164-9
Density: g/cm3
Melting Point: 1035oC
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: reacts
Hazard Symbols: Flammable, dangerous fire risk, ignites in air, store under water or inert gas.
Risk Codes: 14/15-17-34
Safety: Ignites spontaneously in air. Violent reaction with water liberates explosive hydrogen gas. When heated to decomposition it emits toxic fumes of Cl. See also TITANIUM COMPOUNDS.
PSA: 0.00000
LogP: 1.37900
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Chemistry

The molecular formula of  TITANIUM DICHLORIDE is Cl2Ti.

Its molecular weight is about 118.81.And the density of it is 3.13 g/cm3.Melting point is about 1035 °C,boiling point is about 1500°C .TITANIUM DICHLORIDE has the appearance of  black crystals or red-brown solid.
More important,the hazard symbols are that it is flammable,may have dangerous fire risks and can ignite in air .So TITANIUM DICHLORIDE must be stored under water or inert gas.The Ti(II) centers are octahedrally coordinated to six chloride ligands.

Uses

TITANIUM DICHLORIDE can used as decomp by water and sol in alc,almost insol in chloroform, ether, carbon disulfide. Ti(II) is a strong reducing agent.

Production

Molecular complexes are known such as TiCl2, where chel is DMPE  ((CH3)2PCH2CH2P(CH3)2 and TMEDA ((CH3)2NCH2CH2N(CH3)2).The reduction of related Ti(III) and Ti(IV) complexes can prepare certain species.

Na2TiCI4 is a solid-state derivative of TiCl2. And Na2TiCI4 has been prepared by the reaction of Ti metal with TiCl3 in a NaCl flux.This species adopts a linear chain structure,whereas the Ti(II) centers are octahedral with terminal, axial halides.

Safety Profile

Ignites spontaneously in air. Violent reaction with water liberates explosive hydrogen gas. When heated to decomposition it emits toxic fumes of Cl. See also TITANIUM COMPOUNDS.