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CAS No.: | 10049-06-6 |
---|---|
Name: | TITANIUM(II) CHLORIDE |
Article Data: | 46 |
Molecular Structure: | |
Formula: | Cl2Ti |
Molecular Weight: | 118.786 |
Synonyms: | Dichlorotitanium;Titanium dichloride; Titanium(II) chloride |
EINECS: | 233-164-9 |
Density: | g/cm3 |
Melting Point: | 1035oC |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
Solubility: | reacts |
Hazard Symbols: | Flammable, dangerous fire risk, ignites in air, store under water or inert gas. |
Risk Codes: | 14/15-17-34 |
Safety: | Ignites spontaneously in air. Violent reaction with water liberates explosive hydrogen gas. When heated to decomposition it emits toxic fumes of Cl−. See also TITANIUM COMPOUNDS. |
PSA: | 0.00000 |
LogP: | 1.37900 |
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The molecular formula of TITANIUM DICHLORIDE is Cl2Ti.
Its molecular weight is about 118.81.And the density of it is 3.13 g/cm3.Melting point is about 1035 °C,boiling point is about 1500°C .TITANIUM DICHLORIDE has the appearance of black crystals or red-brown solid.
More important,the hazard symbols are that it is flammable,may have dangerous fire risks and can ignite in air .So TITANIUM DICHLORIDE must be stored under water or inert gas.The Ti(II) centers are octahedrally coordinated to six chloride ligands.
Molecular complexes are known such as TiCl2, where chel is DMPE ((CH3)2PCH2CH2P(CH3)2 and TMEDA ((CH3)2NCH2CH2N(CH3)2).The reduction of related Ti(III) and Ti(IV) complexes can prepare certain species.
Na2TiCI4 is a solid-state derivative of TiCl2. And Na2TiCI4 has been prepared by the reaction of Ti metal with TiCl3 in a NaCl flux.This species adopts a linear chain structure,whereas the Ti(II) centers are octahedral with terminal, axial halides.