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10102-06-4

Basic Information
CAS No.: 10102-06-4
Name: URANYL NITRATE
Molecular Structure:
Molecular Structure of 10102-06-4 (URANYL NITRATE)
Formula: N2O8 U
Molecular Weight: 394.038
Synonyms: Uranium,bis(nitrato-O)dioxo-, (T-4)-;Uranium, dinitratodioxo- (8CI);Bis(nitrato-O)dioxouranium;Dinitratodioxouranium;Uranium dinitrate dioxide;Uranium nitrate oxide (U(NO3)2O2);Uranium nitrate oxide (UO2(NO3)2);Uranyldinitrate;Uranyl nitrate;Uranyl nitrate (UO2(NO3)2);
Density: 2.807
Melting Point: 60.2°C
Boiling Point: 118°C
Solubility: g/100g H2O: 98 (0°C), 122 (20°C), 474 (100°C)
Appearance: hygroscopic yellow-green solid
Hazard Symbols: Strong oxidizer. Corrosive and irritating.
Risk Codes: Poison by inhalation. Moderately toxic by ingestion. Human mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. A radioactive material. A powerful explosive and oxidizer. Incompatible with cellulose. Ether solutions in sunlight may explode. When heated to decomposition it emits toxic fumes of NOx. See also URANYL NITRATE HEXAHYDRATE and URANIUM.
PSA: 171.90000
LogP: 0.33060
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Chemistry

IUPAC Name: Dinitrooxy(dioxo)uranium(2-)
CAS: 10102-06-4
Following is the Molecular Structure of Uranyl nitrate (solid) (10102-06-4):

SMILES: [N+](=O)([O-])O[U-2](=O)(=O)O[N+](=O)[O-]
InChI: InChI=1/2NO3.2O.U/c2*2-1(3)4;;;/q2*-1;;;/rN2O8U/c3-1(4)9-11(7,8)10-2(5)6/q-2
InChIKey: QWDZADMNIUIMTC-FNIZAZFDAM
Std.InChI: InChI=1S/2NO3.2O.U/c2*2-1(3)4;;;/q2*-1;;;
Std.InChIKey: QWDZADMNIUIMTC-UHFFFAOYSA-N
Molecular Formula: N2O8U
Molecular Weight: 394.04
Melting Point: 60℃
Boiling Point: 118℃ decomp.
Density: 2.81 g/cm

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD oral > 500mg/kg (500mg/kg)   National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. Vol. 5, Pg. 28, 1953.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes:  T+ Very Toxic. N Dangerous for the environment.
Risk Statements: 26/28-33-51/53
R26/28: Very toxic by inhalation and if swallowed.
R33: Danger of cumulative effects.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 1/2-20/21-45-61
S1/2: Keep locked up and out of the reach of children.
S20/21: When using do not eat, drink or smoke.
S45: In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
S61:  Avoid release to the environment. Refer to special instructions/safety data sheet.
Poison by inhalation. Moderately toxic by ingestion. Human mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. A radioactive material. A powerful explosive and oxidizer. Incompatible with cellulose. Ether solutions in sunlight may explode. When heated to decomposition it emits toxic fumes of NOx .

Standards and Recommendations

OSHA PEL: TWA 0.2 mg(U)/m3; STEL 0.6 mg(U)/m3
ACGIH TLV: TWA 0.2 mg(U)/m3; STEL 0.6 mg(U)/m3
DOT Classification:  7; Label: Radioactive, Oxidizer

Specification

 Uranyl nitrate (solid) (10102-06-4) also can be called for Uranyl nitrate ; Uranyl nitrate (solid):(bis(nitrato-o,o')dioxouranium) ; Uranyl dinitrate ; Uranyl(2+)nitrate,solid ; UO2(NO3)2 . Uranyl nitrate (solid) (10102-06-4) is a yellow-green solid and it's hygroscopic. Uranyl nitrate (solid) (10102-06-4) is an oxidizing and highly toxic compound and should not be ingested; it causes severe renal insufficiency and acute tubular necrosis and is a lymphocyte mitogen. Target organs include the kidneys, liver, lungs and brain. It also represents a severe fire and explosion risk when heated or subjected to shock in contact with oxidizable substances.It was used to fuel aqueous homogeneous reactors in the 1950s. However it proved too corrosive in this application, and the experiments were abandoned. Uranyl nitrate (solid) (10102-06-4) is important for nuclear reprocessing; it is the compound of Uranium that results from dissolving the decladded spent nuclear fuel rods or yellowcake in nitric acid, for further separation and preparation of Uranium hexafluoride for isotope separation for preparing of enriched Uranium .