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10193-36-9

Basic Information
CAS No.: 10193-36-9
Name: tetrahydroxysilane
Article Data: 91
Molecular Structure:
Molecular Structure of 10193-36-9 (tetrahydroxysilane)
Formula: H4O4Si
Molecular Weight: 96.1149
Synonyms: Monosilicicacid;Orthosilicic acid;Orthosilicic acid (H4SiO4);Silicic acid (Si(OH)4);Silicon hydroxide (Si(OH)4);Silicon tetrahydroxide;Tetrahydroxysilane;Tetrahydroxysilicon;
EINECS: 233-477-0
Density: 1.77 g/cm3
Boiling Point: 153-156 °C(Press: 2 Torr)
Solubility: 100ng/L at 25℃
PSA: 80.92000
LogP: -2.60880
Synthetic route
4424-00-4

silicic acid tetrabenzyl ester

10193-36-9

silicic Acid

Conditions
ConditionsYield
With palladium-platinum; hydrogen; aniline In N,N-dimethyl acetamide at 20℃; for 2h; Concentration; Solvent;96%
4424-00-4

silicic acid tetrabenzyl ester

A

20638-18-0

pyrosilicic acid

B

10193-36-9

silicic Acid

Conditions
ConditionsYield
With palladium-platinum; hydrogen; aniline at 20℃; for 2h; Concentration; Reagent/catalyst; Time;A 6%
B 92%
With palladium-platinum; hydrogen In N,N-dimethyl acetamide at 20℃; for 2h;A 34%
B 13%

sodium silicate octahydrate

A

20638-18-0

pyrosilicic acid

B

20638-19-1

cyclo trisiloxanehexaol

C

57956-13-5

(HO)3SiOSi(OH)2OSi(OH)3

D

20761-28-8

(HO)2SiOSi(OH)2OSi(OH)2O(Si(OH)2O)

E

10193-36-9

silicic Acid

Conditions
ConditionsYield
With sulfuric acid Kinetics; byproducts: H10Si6O17, H10Si8O21, polysilicate; Na2H2SiO4*8H2O added to zeolite ion-exchange/H2SO4 at 2°C; filtered, product yield dependence to ageing time at room temp.;A 14%
B n/a
C n/a
D 5%
E 51%
4424-00-4

silicic acid tetrabenzyl ester

A

20638-18-0

pyrosilicic acid

B

20638-19-1

cyclo trisiloxanehexaol

C

10193-36-9

silicic Acid

Conditions
ConditionsYield
With palladium-platinum; hydrogen at 20℃; for 2h;A 36%
B 47%
C 8%
sodium silicate

sodium silicate

A

20638-18-0

pyrosilicic acid

B

20638-19-1

cyclo trisiloxanehexaol

C

57956-13-5

(HO)3SiOSi(OH)2OSi(OH)3

D

20761-28-8

(HO)2SiOSi(OH)2OSi(OH)2O(Si(OH)2O)

E

10193-36-9

silicic Acid

Conditions
ConditionsYield
With sulfuric acid Kinetics; byproducts: H10Si6O17, H10Si8O21, polysilicate; Na2SiO3 added to zeolite ion-exchange/H2SO4 at 2°C; filtered, product yield dependence to ageing time at room temp.;A 8%
B n/a
C n/a
D 4%
E 28%
ammonia

ammonia

silica gel

silica gel

7646-78-8

tin(IV) chloride

A

tin hydroxide

B

10193-36-9

silicic Acid

Conditions
ConditionsYield
In water pH=5 - 7;
681-84-5

tetramethylorthosilicate

10193-36-9

silicic Acid

Conditions
ConditionsYield
In neat (no solvent) Kinetics; solid SiO2 reacted with H2O vapor;
7664-93-9

sulfuric acid

7440-21-3

silicon

A

10193-36-9

silicic Acid

B

7704-34-9

sulfur

7440-21-3

monosilane

A

7647-01-0

hydrogenchloride

B

mercury(I) chloride

C

10193-36-9

silicic Acid

Conditions
ConditionsYield
With water; mercury dichloride In water
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  • Silicic acid (H4SiO4)

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Specification

The Monosilicic acid, with the CAS registry number 10193-36-9, is also known as Orthosilicic acid. It belongs to the product category of Inorganics. Its EINECS registry number is 233-477-0. This chemical's molecular formula is H4O4Si and molecular weight is 96.11486. Its IUPAC name is called silicic acid.

Physical properties of Monosilicic acid: (1)ACD/LogP: 0.65; (2)ACD/LogD (pH 5.5): 0.65; (3)ACD/LogD (pH 7.4): 0.65; (4)ACD/BCF (pH 5.5): 1.84; (5)ACD/BCF (pH 7.4): 1.84; (6)#H bond acceptors: 4; (7)#H bond donors: 4; (8)#Freely Rotating Bonds: 4; (9)Index of Refraction: 1.535; (10)Molar Refractivity: 16.9 cm3; (11)Molar Volume: 54.2 cm3; (12)Surface Tension: 72.1 dyne/cm; (13)Density: 1.77 g/cm3.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: O[Si](O)(O)O
(2)InChI: InChI=1S/H4O4Si/c1-5(2,3)4/h1-4H
(3)InChIKey: RMAQACBXLXPBSY-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LDLo intraperitoneal 120mg/kg (120mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
British Journal of Experimental Pathology. Vol. 3, Pg. 75, 1922.
guinea pig LDLo intravenous 100mg/kg (100mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: MUSCLE WEAKNESS

BEHAVIORAL: TREMOR
British Journal of Experimental Pathology. Vol. 3, Pg. 75, 1922.
mouse LDLo intraperitoneal 40mg/kg (40mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: TREMOR

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
British Journal of Experimental Pathology. Vol. 3, Pg. 75, 1922.
mouse LDLo intravenous 100mg/kg (100mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BLOOD: CHANGE IN CLOTTING FACTORS

BEHAVIORAL: MUSCLE WEAKNESS
British Journal of Experimental Pathology. Vol. 3, Pg. 75, 1922.
rabbit LDLo intravenous 100mg/kg (100mg/kg) BEHAVIORAL: EXCITEMENT

CARDIAC: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
British Journal of Experimental Pathology. Vol. 3, Pg. 75, 1922.
rat LDLo intravenous 100mg/kg (100mg/kg) BLOOD: CHANGE IN CLOTTING FACTORS British Journal of Experimental Pathology. Vol. 3, Pg. 75, 1922.