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136-35-6

Basic Information
CAS No.: 136-35-6
Name: 1,3-Diphenyltriazene
Article Data: 5
Molecular Structure:
Molecular Structure of 136-35-6 (1,3-Diphenyltriazene)
Formula: C12H11 N3
Molecular Weight: 197.239
Synonyms: Triazene,1,3-diphenyl- (6CI,7CI,8CI); 1,3-Diphenyltriazene; Aniline, N-(phenylazo)-;Diazoaminobenzene; NSC 2077
EINECS: 205-240-1
Density: 1.07 g/cm3
Melting Point: 96 ºC
Boiling Point: 304.9 ºC at 760 mmHg
Flash Point: 138.2 ºC
Solubility: 499.8mg/L(room temperature)
Appearance: ochre powder
Hazard Symbols: Explodes on heating to 150C dangerous.
Risk Codes: 1-5-20/21/22-36/37/38
Safety: Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Strongly explosive when shocked or heated to 98°C. Mixture with acetic anhydride explodes when warmed. When heated to decomposition it emits toxic fumes of NOx.
PSA: 36.75000
LogP: 3.87040
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Chemistry

IUPAC Name: N-Phenyldiazenylaniline
The molecular formula of 1,3-Diphenyltriazene (CAS NO.136-35-6) is C12H11N3.

                             
The molecular weight of 1,3-Diphenyltriazene (CAS NO.136-35-6) is 197.24.
Synonyms of 1,3-Diphenyltriazene (CAS NO.136-35-6): Benzeneazoanilide ; 1-Triazene, 1,3-diphenyl-, (1E)- ; 1,3-Diphenyltriaz-1-ene ; 1-Triazene, 1,3-diphenyl-
Product Categories: Pharmaceutical Intermediates
Index of Refraction: 1.592  
Apperance: ochre powder
EINECS: 205-240-1
Density: 1.07 g/ml 
Flash Point: 138.2 °C 
Boiling Point: 304.9 °C 
Melting Point: 96 °C

Uses

  1,3-Diphenyltriazene (CAS NO.136-35-6) is used as organic synthesis intermediates  for the preparation of p-aminoazobenzene; as dye intermediates for the synthesis of azo dyes, disperse dyes, oxazine dyes; also used as a foaming agent, curing agent and initiator.

Production

From the reaction of aniline and sodium nitrite, and then condensation with the aniline.

Toxicity Data With Reference

1.    

mmo-sat 300 ng/plate

    ENMUDM    Environmental Mutagenesis. 9 (Suppl 9)(1987),1.

Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Safety Profile

Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Strongly explosive when shocked or heated to 98°C. Mixture with acetic anhydride explodes when warmed. When heated to decomposition it emits toxic fumes of NOx.