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14077-30-6

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Basic Information
CAS No.: 14077-30-6
Name: TRANS-DICHLOROTETRAKIS(PYRIDINE)RHODIUM&
Article Data: 21
Molecular Structure:
Molecular Structure of 14077-30-6 (TRANS-DICHLOROTETRAKIS(PYRIDINE)RHODIUM&)
Formula: C20H20 Cl2 N4 Rh . Cl
Molecular Weight: 615.746
Synonyms: Rhodium(1+),dichlorotetrakis(pyridine)-, chloride, (OC-6-12)- (9CI); Rhodium(1+),dichlorotetrakis(pyridine)-, chloride, trans- (8CI); NSC 156311;trans-Dichlorotetra(pyridine)rhodium(III)chloride;trans-Dichlorotetrakis(pyridine)rhodium(1+) chloride;trans-Dichlorotetrakis(pyridine)rhodium(1+) monochloride;trans-Dichlorotetrakis(pyridine)rhodium(III) chloride
Density: g/cm3
Melting Point: 285 °C (dec.)(lit.)
Boiling Point: 115.3°Cat760mmHg
Flash Point: 20°C
Hazard Symbols:
Risk Codes: 36/37/38
Safety: Mutation data reported. When heated to decomposition it emits toxic vapors of NOx, Rh, and Cl−.
PSA: 12.96000
LogP: 4.87700
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Chemistry

IUPAC Name: Pyridine; rhodium(3+); trichloride 
Molecular Formula: C20H20Cl2N4Rh•Cl
Molecular Weight: 525.70
EINECS: 237-929-8
Melting Point: 285 °C (dec.)(lit.)
Boiling Point: 115.3°C at 760mmHg
Flash Point: 20°C
Freely Rotating Bonds: 0
Polar Surface Area: 12.89 Å2
Enthalpy of Vaporization: 35.09 kJ/mol
Vapour Pressure: 22.8 mmHg at 25°C 
Form: powder
The Cas Register Number of trans-Dichlorotetrakis(pyridine)-rhodium chloride is 14077-30-6.The chemical synonyms of trans-Dichlorotetrakis(pyridine)-rhodium chloride (CAS NO.14077-30-6) are Dichlorotetrakis(pyridine)-,chloride,(e)-rhodium(1+ ; trans-Dichlorotetrakis(pyridine)rhodiumchloride ; Trans-dichlorotetrakis(pyridine)rhodium ; Dichlorotetrakis(pyridine)rhodium chloride ; Dichlorotetrapyridinorhodium chloride .The molecular structure of trans-Dichlorotetrakis(pyridine)-rhodium chloride (CAS NO.14077-30-6) is.

Uses

 trans-Dichlorotetrakis(pyridine)-rhodium chloride (CAS NO.14077-30-6) is used as detergent.

Toxicity Data With Reference

1.    

mic-sat 50 nmol/plate

     MUREAV    Mutation Research. 88 (1981),165.

Safety Profile

Mutation data reported. When heated to decomposition it emits toxic vapors of NOx, Rh, and Cl−.
Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36: Wear suitable protective clothing.
WGK Germany: 3
RTECS: VI9310000

Standards and Recommendations

ACGIH TLV: TWA 1 mg(Rh)/m3. Not Classifiable as a human carcinogen.