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1569-02-4

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Basic Information
CAS No.: 1569-02-4
Name: 1-Ethoxy-2-propanol
Article Data: 31
Molecular Structure:
Molecular Structure of 1569-02-4 (1-Ethoxy-2-propanol)
Formula: C5H12O2
Molecular Weight: 104.149
Synonyms: Ethyl Proxitol;NSC 2404;
EINECS: 216-374-5
Density: 0.903 g/cm3
Melting Point: -100 °C
Boiling Point: 131 °C at 760 mmHg
Flash Point: 45.9 °C
Solubility: soluble
Appearance: Clear colorless liquid
Hazard Symbols: R10:; R67:;
Risk Codes: 67-10
Safety: 24
PSA: 29.46000
LogP: 0.40370
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Conditions
ConditionsYield
With Al2O3/MgO composite at 120℃; Inert atmosphere;37.2%
With sodium ethanolate
With sodium hydroxide
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diethyl sulfate

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Conditions
ConditionsYield
at 90 - 100℃; in alkal.Loesung;
With sodium hydroxide at 100℃;
With sodium hydroxide at 100℃;
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methyloxirane

A

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B

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Conditions
ConditionsYield
With H+-Zeolite X at 35℃; for 24h; Product distribution; Mechanism; other 2-substituted epoxides; other alcohols, thiols and amine as nucleophiles; var. solid-catalysts; also H2SO4 as catalyst; var. temp.;
With sulfuric acid
With boron trifluoride
...Expand
64-17-5

ethanol

141-52-6

sodium ethanolate

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methyloxirane

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...Expand
141-52-6

sodium ethanolate

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methyloxirane

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Conditions
ConditionsYield
In ethanol
3054-95-3

acrylaldehyde diethyl acetal

A

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3,3-diethoxypropan-1-ol

B

1569-02-4

propylene glycol monoethyl ether

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide; bis-(1,2-dimethylpropyl)borane Product distribution; 1)THF, 0 deg C, 7 h;A 90.5 % Chromat.
B 1 % Chromat.
64-17-5

ethanol

75-56-9, 16033-71-9

methyloxirane

A

1569-02-4

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B

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di(propylene glycol) ethyl ether

Conditions
ConditionsYield
With sodium hydroxide Heating; Yield given. Yields of byproduct given;
...Expand
64-17-5

ethanol

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methyloxirane

sodium hydroxide

sodium hydroxide

1569-02-4

propylene glycol monoethyl ether

...Expand
64-67-5

diethyl sulfate

57-55-6

propylene glycol

A

1569-02-4

propylene glycol monoethyl ether

B

propylene glycol-diethyl ether

propylene glycol-diethyl ether

...Expand
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1-bromo-2-ethoxy-propane

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water

A

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B

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Conditions
ConditionsYield
at 100℃;
...Expand
Raw Materials
3054-95-3
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14869-34-2
54839-24-6
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Chemistry

Structure of 2-Propanol, 1-ethoxy- (CAS NO.1569-02-4):

IUPAC Name: 1-ethoxypropan-2-ol 
Empirical Formula: C5H12O2
Molecular Weight: 104.1476 
EINECS: 216-374-5 
Index of Refraction: 1.408
Molar Refractivity: 28.45 cm3
Molar Volume: 115.3 cm3
Polarizability: 11.27×10-24cm3
Surface Tension: 27.8 dyne/cm
Density: 0.903 g/cm3
Flash Point: 45.9 °C
Enthalpy of Vaporization: 42.95 kJ/mol 
Melting Point: -100 °C
Boiling Point: 131 °C at 760 mmHg
Vapour Pressure: 4.21 mmHg at 25°C 
Water Solubility: soluble 
Physical Appearance: Clear colorless liquid
Synonyms of 2-Propanol, 1-ethoxy- (CAS NO.1569-02-4): 1-Ethoxy-2-propanol ; 4-01-00-02471 (Beilstein Handbook Reference) ; Propylene glycol ethyl ether

Uses

  2-Propanol, 1-ethoxy- (CAS NO.1569-02-4) is used in coatings, inks, photosensitive plastic etc.

Toxicity Data With Reference

1.    

orl-rat LD50:4400 mg/kg

     NPIRI*    Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),104.
2.    

skn-rbt LD50:8100 mg/kg

     NPIRI*    Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),104.

Consensus Reports

Glycol ether compounds are on the Community Right-To-Know List.

Safety Profile

Mildly toxic by ingestion and skin contact. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.
Risk Statements: 67-10 
R67:Vapours may cause drowsiness and dizziness. 
R10:Flammable.
Safety Statements: 24 
S24:Avoid contact with skin.
RIDADR: 1987
RTECS: UB5250000
HazardClass: 3
PackingGroup: III