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2114-18-3

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Basic Information
CAS No.: 2114-18-3
Name: 2-Chloroethyl carbamate
Article Data: 16
Molecular Structure:
Molecular Structure of 2114-18-3 (2-Chloroethyl carbamate)
Formula: C3H6ClNO2
Molecular Weight: 123.539
Synonyms: Carbamicacid, 2-chloroethyl ester (6CI,7CI);Ethanol, 2-chloro-, carbamate (8CI,9CI);NSC 31185;b-Chloroethyl carbamate;
EINECS: 218-310-1
Density: 1.278 g/cm3
Melting Point: 74-77 °C(lit.)
Boiling Point: 264.3 °C at 760 mmHg
Flash Point: 113.7 °C
Hazard Symbols: HarmfulXn
Risk Codes: 22-36/37/38
Safety: 36/37/39-45
PSA: 52.32000
LogP: 1.02080
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Chemistry

IUPAC Name: 2-Chloroethyl carbamate
Synonyms of β-Chloroethyl carbamate (CAS NO.2114-18-3): 2-Chloroethanol carbamate ; 2-Chloroethyl carbamate ; Carbamic acid, 2-chloroethyl ester ; Carbamic acid, beta-chloroethyl ester ; Chloroethyl carbamate ; Carbamic acid, 2-chloroethyl ester (9CI) ; Ethanol, 2-chloro-, 1-carbamate ; Ethanol, 2-chloro-, carbamate
CAS NO:2114-18-3
Molecular Formula: C3H6ClNO2
Molecular Weight : 123.54
Molecular Structure:
EINECS: 218-310-1
H bond acceptors: 3
H bond donors: 2
Freely Rotating Bonds: 3
Polar Surface Area: 29.54 Å2
Index of Refraction: 1.452
Molar Refractivity: 26.1 cm3
Molar Volume: 96.5 cm3
Surface Tension: 40.5 dyne/cm
Density: 1.278 g/cm3
Flash Point: 113.7 °C
Enthalpy of Vaporization: 50.22 kJ/mol
Boiling Point: 264.3 °C at 760 mmHg
Vapour Pressure: 0.00976 mmHg at 25°C
Melting Point: 74-77 °C(lit.)
Appearance: White or slightly yellow crystal.

Uses

 β-Chloroethyl carbamate (CAS NO.2114-18-3) is used as intermediates in pharmaceutical and organic .

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 1gm/kg (1000mg/kg) BEHAVIORAL: GENERAL ANESTHETIC Journal of the National Cancer Institute. Vol. 8, Pg. 99, 1947.
mouse LD50 oral 950mg/kg (950mg/kg)   Therapie. Vol. 16, Pg. 678, 1961.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 22-36/37/38
R22: Harmful if swallowed. 
R36/37/38: β-Chloroethyl carbamate (CAS NO.2114-18-3) is irritating to eyes, respiratory system and skin.
Safety Statements; 36/37/39-45
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
WGK Germany: 3
RTECS: EZ1475000

Moderately toxic by ingestion and intraperitoneal routes. See also CARBAMATES. When heated to decomposition it emits very toxic fumes of Cl− and NOx.