Name: TRI-N-BUTYLGERMANIUM CHLORIDE
SKU: 2117-36-4

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Basic Information

Molecular Structure:
CAS No.:	2117-36-4
Name:	TRI-N-BUTYLGERMANIUM CHLORIDE
Article Data:	19

Formula:	C12H27 Cl Ge
Molecular Weight:	279.389
Synonyms:	Chlorotributylgermane;Tributylchlorogermane; Tributylgermanium chloride; Tributylgermyl chloride
EINECS:	218-323-2
Density:	1.054 g/mL at 25 °C(lit.)
Boiling Point:	270 °C(lit.)
Flash Point:	>230 °F
Hazard Symbols:	C
Risk Codes:	34-20/21/22
Safety:	Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of Cl⁻. See also GERMANIUM COMPOUNDS.
PSA:	0.00000
LogP:	5.57100

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Chemistry

IUPAC Name: Tributyl(chloro)germane
Synonyms of Chlorotributylgermanium (CAS NO.2117-36-4): Tributylchlorogermane ; Germane, tributylchloro- ; Germanium, chlorotributyl-
CAS NO: 2117-36-4
Molecular Formula: C₁₂H₂₇ClGe
Molecular Weight : 279.4358
Molecular Structure:
EINECS: 218-323-2
Flash Point: 97.8 °C
Enthalpy of Vaporization: 51.22 kJ/mol
Boiling Point: 294 °C at 760 mmHg
Vapour Pressure: 0.00293 mmHg at 25°C
Refractive index: n20/D 1.465(lit.)
Appearance: Clear colorless liquid

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	1280mg/kg (1280mg/kg)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1243, 1986.
mouse	LDLo	intraperitoneal	1280mg/kg (1280mg/kg)	PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Comptes Rendus des Seances de l'Academie des Sciences, Serie D: Sciences Naturelles. Vol. 262, Pg. 1302, 1966.
rat	LD50	oral	1970mg/kg (1970mg/kg)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1243, 1986.
rat	LDLo	intraperitoneal	1970mg/kg (1970mg/kg)	PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Comptes Rendus des Seances de l'Academie des Sciences, Serie D: Sciences Naturelles. Vol. 262, Pg. 1302, 1966.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: Corrosive C
Risk Statements: 34-20/21/22
R34: Chlorotributylgermanium (CAS NO.2117-36-4) can causes burns.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 45-36/37/39-26
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
TSCA: Yes

Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of Cl⁻. See also GERMANIUM COMPOUNDS.

Specification

1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
2.Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
3.Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
4.Storage: Store Chlorotributylgermanium (CAS NO.2117-36-4) in a cool, dry place. Store in a tightly closed container. Corrosives area. Store under nitrogen.