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21368-68-3

Basic Information
CAS No.: 21368-68-3
Name: DL-Camphor
Article Data: 9
Molecular Structure:
Molecular Structure of 21368-68-3 (DL-Camphor)
Formula: C10H16O
Molecular Weight: 152.236
Synonyms: Dehydrocamphor; 2-Oxo-bornan; 3-Fluor-2,2-dimethyl-bicyclo<2.2.1>heptan; Camphen-hydrofluorid;
EINECS: 200-945-0
Density: 0.992
Melting Point: 175oC
Boiling Point: 204oC
Flash Point: 64oC
Appearance: White powder with a penetrating, aromatic odor.
Hazard Symbols: R22:;
Risk Codes:  Xn:Harmful;
">  Xn:Harmful;
Safety: 16-26-36
PSA: 17.07000
LogP: 2.40170
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    DL-Camphor

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Chemistry

 DL-Camphor (21368-68-3) is called for camphor ; DL-Camphor ; Formosa camphor ; Laurel camphor ; 2-Bornanone ; Gum camphor ; Alcanfor ; Alphanon ; Kampfer ; Root bark oil ; 1,7,7-Trimethylnorbornan-2-one ; DL-1,7,7-Trimethylbicyclo[2.2.1]hepta-2-one ,and so on. DL-Camphor (21368-68-3) is  usually white powder with a penetrating, aromatic odor.

IUPAC Name: 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
CAS: 21368-68-3
Molecular Formula: C10H16O
Molecular Weight: 152.23
Molecular structure:
EINECS: 200-945-0
Melting point:  175-177 °C(lit.)
ACD/LogD (pH 5.5): 2.13 
ACD/LogD (pH 7.4): 2.13 
ACD/BCF (pH 5.5): 24.39 
ACD/BCF (pH 7.4): 24.39 
ACD/KOC (pH 5.5): 342.47 
ACD/KOC (pH 7.4): 342.47 
H bond acceptors: 1 
H bond donors: 0 
Freely Rotating Bonds: 0 
Index of Refraction: 1.485 
Molar Refractivity: 44.39 cm3 
Molar Volume: 154.8 cm3 
Polarizability: 17.59 10-24cm3 
Surface Tension: 31.5 dyne/cm 
Density: 0.982 g/cm3 
Flash Point: 64.4 °C 
Enthalpy of Vaporization: 44.37 kJ/mol 
Boiling Point: 207.4 °C at 760 mmHg 
Vapour Pressure: 0.225 mmHg at 25°C

Uses

1. DL-Camphor (21368-68-3) is sometimes used in a preservative for books.
2. DL-Camphor (21368-68-3) is used as a plasticizer in cellulose nitrate plastics.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo intraperitoneal 400mg/kg (400mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
child LDLo unreported 100mg/kg (100mg/kg)   Yakkyoku. Pharmacy. Vol. 31, Pg. 1499, 1980.
child TDLo oral 51mg/kg (51mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
American Journal of Emergency Medicine. Vol. 7, Pg. 41, 1989.
 
dog LDLo oral 800mg/kg (800mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
frog LDLo subcutaneous 240mg/kg (240mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 50, Pg. 199, 1903.
infant LDLo oral 70mg/kg (70mg/kg) SENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
American Journal of Pathology. Vol. 30, Pg. 857, 1954.
 
man LDLo unreported 29mg/kg (29mg/kg)   "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
mouse LCLo inhalation 400mg/m3/3H (400mg/m3) BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 22(11), Pg. 83, 1957.
mouse LD50 intraperitoneal 3gm/kg (3000mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: REGIDITY

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
American Journal of Pathology. Vol. 30, Pg. 857, 1954.
 
mouse LD50 oral 1310mg/kg (1310mg/kg)   Shika Gakuho. Journal of Dentistry. Vol. 75, Pg. 934, 1975.
 
mouse LDLo subcutaneous 200mg/kg (200mg/kg) BEHAVIORAL: EXCITEMENT "Pharmakologische Prufung von Analgetika, Dissertation," Herrlen, G., Pharmakologischen Institut der Universitat Tubingen, Fed. Rep. Ger., 1933Vol. -, Pg. -, 1933.
rabbit LDLo oral 2gm/kg (2000mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

BEHAVIORAL: REGIDITY
American Journal of Pathology. Vol. 30, Pg. 857, 1954.
 
rat LD50 subcutaneous 70mg/kg (70mg/kg)   "Ueber die Pharmakologische Wirkung eines dem Pentamethylentetrazol Vol. -, Pg. -, 1934.
rat LDLo intraperitoneal 900mg/kg (900mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Journal of Pharmacology and Experimental Therapeutics. Vol. 65, Pg. 275, 1939.

RTECS:  EX1225000

Safety Profile

Hazard Codes:  F,Xn  
Risk Statements:  11-22-36/37/38-36-20/21/22 (R11:Highly flammable. R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin. R36:Irritating to eyes. R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.)
Safety Statements:  16-26-36 (S16:Keep away from sources of ignition. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36:Wear suitable protective clothing.)
RIDADR:  UN 2717 4.1/PG 3
WGK Germany:  1
 

Specification

Removal in wastewater treatment of DL-Camphor (21368-68-3) can be stated as follows:
Total removal:7.85  percent
Total biodegradation:0.11  percent
Total sludge adsorption:3.79  percent
Total to Air:3.96  percent
(using 10000 hr Bio P,A,S)