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| CAS No.: | 26388-85-2 |
|---|---|
| Name: | PERCHLORIC ACID, NICKEL(II) SALT compounded with OCTAMETHYL PYROPHOSPHORAMIDE |
| Molecular Structure: | |
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| Formula: | C24H72N12NiO9P6•2ClO4 |
| Molecular Weight: | 1116.51 |
| Density: | g/cm3 |
| Boiling Point: | 319.6°Cat760mmHg |
| Flash Point: | 147.1°C |
| Safety: | Confirmed human carcinogen. Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx, POx, and Cl−. See also PERCHLORATES and NICKEL COMPOUNDS. |
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Chemistry
Empirical Formula of Perchloric acid, nickel(II) salt, compd. with octamethyl pyrophosphoramide (CAS NO.26388-85-2): C24H72Cl2N12NiO17P6
Molecular Weight: 1116.3407
Flash Point: 147.1 °C
Enthalpy of Vaporization: 56.12 kJ/mol
Boiling Point: 319.6 °C at 760 mmHg
Vapour Pressure: 0.000335 mmHg at 25 °C
Structure of Perchloric acid, nickel(II) salt, compd. with octamethyl pyrophosphoramide (CAS NO.26388-85-2):
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IUPAC Name: N-[Bis(dimethylamino)phosphoryloxy-(dimethylamino)phosphoryl]-N-methylmethanamine; nickel(2+); diperchlorate
Canonical SMILES: CN(C)P(=O)(N(C)C)OP(=O)(N(C)C)N(C)C.CN(C)P(=O)(N(C)C)OP(=O)(N(C)C)N(C)C.CN(C)P(=O)(N(C)C)OP(=O)(N(C)C)N(C)C.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Ni+2]
InChI: InChI=1S/3C8H24N4O3P2.2ClHO4.Ni/c3*1-9(2)16(13,10(3)4)15-17(14,11(5)6)12(7)8;2*2-1(3,4)5;/h3*1-8H3;2*(H,2,3,4,5);/q;;;;;+2/p-2
InChIKey: SHVNRAPGSBXVMS-UHFFFAOYSA-L
Toxicity Data With Reference
| 1. | ipr-mus LD50:15 mg/kg | JAFCAU Journal of Agricultural and Food Chemistry. 14 (1966),512. |
Consensus Reports
NTP 10th Report on Carcinogens. Nickel and its compounds are on the Community Right-To-Know List.
Safety Profile
Confirmed human carcinogen. Poison by intraperitoneal route. When heated to decomposition Perchloric acid, nickel(II) salt, compd. with octamethyl pyrophosphoramide (CAS NO.26388-85-2) emits very toxic fumes of NOx, POx, and Cl−. See also PERCHLORATES and NICKEL COMPOUNDS.
Standards and Recommendations
NIOSH REL: TWA 0.015 mg(Ni)/m3
Specification
Perchloric acid, nickel(II) salt, compd. with octamethyl pyrophosphoramide , its cas register number is 26388-85-2. It also can be called Nickel(2+), tris(octamethyldiphosphoramide-Op,Op')-, (OC-6-11)-, diperchlorate ; and Nickel(2+), tris(octamethylpyrophosphoramide)-, diperchlorate .