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| CAS No.: | 3497-00-5 |
|---|---|
| Name: | PHENYLTHIOPHOSPHONIC DICHLORIDE |
| Article Data: | 46 |
| Molecular Structure: | |
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|
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| Formula: | C6H5Cl2PS |
| Molecular Weight: | 211.051 |
| Synonyms: | Phenylthiophosphonyl dichloride;Phenylphosphonothioic Dichlorid;Phosphonothioicdichloride, phenyl- (6CI,7CI,8CI,9CI);Dichlorophenylphosphine sulfide;NSC62217;Phenylphosphonothioic chloride;Phenylphosphonothioic dichloride;Phenylphosphonothionodichloridic acid;Phenylphosphonothioyl dichloride;Phenylphosphorus thiodichloride;Phenylthionophosphonic dichloride; |
| EINECS: | 222-494-9 |
| Density: | 1.43 g/cm3 |
| Melting Point: | < -20oC |
| Boiling Point: | 271.2 °C at 760 mmHg |
| Flash Point: | 117.8 °C |
| Solubility: | 1.522g/L(23 oC) |
| Appearance: | Colorless liquid with unpleasant acrid pungent odor |
| Hazard Symbols: | C |
| Risk Codes: | 34 |
| Safety: | 26-36/37/39 |
| Transport Information: | UN 2799 |
| PSA: | 41.90000 |
| LogP: | 3.74960 |
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Chemistry
IUPAC Name: Dichloro-phenyl-sulfanylidene-λ5-phosphane
Synonyms: Dichloro(phenyl)phosphinesulphide ; Phenyl phosphorus thiodichloride ; Phenyl-phosphonothioicdichlorid ; Phenylphosphonothionodichloridate ; Phenylphosphonothioyl dichloride ; Phenylphosphonothioyldichloride ; Phenylphosphorusthiodichloride ; Phenylthionophosphonic dichloride
CAS NO: 3497-00-5
Molecular Formula of Phenyl phosphorus thiodichloride (CAS NO.3497-00-5) : C6H5Cl2PS
Molecular Weight of Phenyl phosphorus thiodichloride (CAS NO.3497-00-5) : 211.05
Molecular Structure of Phenyl phosphorus thiodichloride (CAS NO.3497-00-5) : 
EINECS: 222-494-9
Mol File: 3497-00-5.mol
Index of Refraction: 1.596
Surface Tension: 51.3 dyne/cm
Density: 1.43 g/cm3
Flash Point: 117.8 °C
Enthalpy of Vaporization: 48.89 kJ/mol
Boiling Point: 271.2 °C at 760 mmHg
Vapour Pressure: 0.0109 mmHg at 25
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
A corrosive. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Statements 34
R34: Phenyl phosphorus thiodichloride (CAS NO.3497-00-5) causes burns.
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR 2799
Standards and Recommendations
DOT Classification: 8; Label: Corrosive
Specification
1.General Description :Colorless liquid with unpleasant acrid pungent odor. Corrodes metals slowly.
2.Air & Water Reactions: Flammable. Decomposes to give hydrochloric acid in water, although this reaction is slow. The reaction becomes vigorous if the water is hot.
3.Reactivity Profile: Phenyl phosphorus thiodichloride (CAS NO.3497-00-5) is water reactive. Incompatible with strong oxidizing agents, alcohols, amines, alkali. Contact with active metals generates flammable hydrogen gas. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts.
4.Health Hazard: corrosive and/or toxic; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.
5.Fire Hazard : except for acetic anhydride (un1715), that is flammable, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.