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505-48-6

Basic Information
CAS No.: 505-48-6
Name: Suberic acid
Article Data: 275
Molecular Structure:
Molecular Structure of 505-48-6 (Suberic acid)
Formula: C8H14O4
Molecular Weight: 174.197
Synonyms: 1,6-Dicarboxyhexane;1,6-Hexanedicarboxylic acid;1,8-Octanedioicacid;Cork acid;Hexamethylenedicarboxylic acid;NSC 25952;NSC 53777;
EINECS: 208-010-9
Density: 1.162 g/cm3
Melting Point: 141-144 °C
Boiling Point: 361.2 °C at 760 mmHg
Flash Point: 186.5 °C
Solubility: 0.6 g/L (20 °C) in water
Appearance: off-white crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36-36/37/38
Safety: 26-39-36
PSA: 74.60000
LogP: 1.49620
Synthetic route
502-49-8

cycloactanone

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity;98%
With dihydrogen peroxide In water; acetonitrile at 90℃; for 11h; Green chemistry;92%
With dihydrogen peroxide; ortho-tungstic acid In water at 90℃; for 20h;85%
629-40-3

octanedinitrile

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
enzyme from Synechocystis sp. PCC 6803 In phosphate buffer at 30℃; for 2h;98%
With water for 48h; Rhodococcus rhodochrous AJ270;78%
With potassium phosphate buffer; Rhodococcus sp. AJ270 at 30℃; for 48h;78%
With hydrogenchloride at 100℃;
931-88-4, 931-87-3

(Z)-Cyclooctene

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With periodic acid; ruthenium trichloride In water at 20℃; for 1.5h; Product distribution; Further Variations:; Solvents;97%
With sodium periodate; 2C16H13N2O10Ru2(1-)*Ca(2+) In water at 45℃; for 16h; Green chemistry;95%
With tert.-butylhydroperoxide; indium(III) chloride In water at 90℃; for 8h;94%
629-41-4

1,8-Octanediol

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With C24H33IrN4O3; water; sodium hydroxide for 18h; Reflux;97%
With sodium bromate; sodium hydrogensulfite In acetonitrile for 2h; Heating;91%
With Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium chloride; oxygen In 1,2-dichloro-ethane at 25℃; for 48h;86%
With Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium chloride; oxygen In 1,2-dichloro-ethane at 20℃; for 48h; Schlenk technique;86%
696-71-9

cyclooctanol

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With oxygen; sodium nitrite In trifluoroacetic acid at 0 - 20℃; for 5h;94%
With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity;94%
Stage #1: cyclooctanol With Oxone; ruthenium(III) chloride monohydrate In water at 70℃; for 8h;
Stage #2: In ethanol Cooling;
89%
With dihydrogen peroxide In water; acetonitrile at 90℃; for 11.5h; Green chemistry;86%
505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With sodium periodate; RuCl3*2.9H2O In water at 20℃; for 0.5h; Sonication;93%
With (tetra-n-butyl-ammonium)3(tetra(oxodiperoxotungstato)phosphate); dihydrogen peroxide In water at 90℃; for 3h;87%
Stage #1: 1,2-cyclooctene With oxygen; ozone In tetrahydrofuran at 0℃;
Stage #2: With hydroxylamine hydrochloride In tetrahydrofuran at 0 - 20℃; Reagent/catalyst; Inert atmosphere;
70%
931-88-4, 931-87-3

(Z)-Cyclooctene

oxone

oxone

Os(VIII)

Os(VIII)

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium sulfate; OsO4 In ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol92%
13154-28-4

2-nitrocyclooctanone

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With dihydrogen peroxide; potassium carbonate In methanol for 10h; Ambient temperature;89%
With Oxone; sodium hydroxide; disodium hydrogenphosphate; water 1.) MeOH, 70 deg C, 4 h, 2.) MeOH, r.t., 4 h; Yield given. Multistep reaction;
65111-06-0

oct-4-ynedioic acid

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol for 15h;88%
With palladium 10% on activated carbon; hydrogen In ethanol for 14h; Inert atmosphere;68%
2050-23-9

diethyl suberate

505-48-6

octane-1,8-dioic acid

Conditions
ConditionsYield
Stage #1: diethyl suberate With iron(III) chloride In tetrachloromethane at 85℃; for 24h; Inert atmosphere;
Stage #2: With hydrogenchloride; water In tetrachloromethane Inert atmosphere;
88%
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    Name Suberic acid Synonyms Octanedioic acid Molecular Structure Molecular Formula C8H14O4

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    Product name: Suberic Acid CAS No.: 505-48-6 Molecule Formula:C8H14O4 Molecule Weight:174.18 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING ITEMS

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Specification

The IUPAC name of Suberic acid is octanedioic acid. With the CAS registry number 505-48-6, it is also named as 1,6-Hexanedicarboxylic acid. The product's categories are Miscellaneous Natural Products; alpha,omega-Alkanedicarboxylic Acids; alpha,omega-Bifunctional Alkanes; Monofunctional & alpha,omega-Bifunctional Alkanes. It is off-white crystalline powder which is soluble in water, ether and ethanol, almost insoluble in chloroform. What's more, it is stable, combustible and incompatible with strong oxidizing agents, reducing agents, bases. Additioanlly, this chemical should be sealed in the container and stored in the ventilate and dry place.

The other characteristics of this product can be summarized as: (1)ACD/LogP: 0.80; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.81; (4)ACD/LogD (pH 7.4): -3.82; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1.58; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 4; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 7; (12)Index of Refraction: 1.475; (13)Molar Refractivity: 42.24 cm3; (14)Molar Volume: 149.8 cm3; (15)Polarizability: 16.74×10-24 cm3; (16)Surface Tension: 47.8 dyne/cm; (17)Enthalpy of Vaporization: 66.68 kJ/mol; (18)Vapour Pressure: 3.37E-06 mmHg at 25°C; (19)Rotatable Bond Count: 7; (20)Exact Mass: 174.089209; (21)MonoIsotopic Mass: 174.089209; (22)Topological Polar Surface Area: 74.6; (23)Heavy Atom Count: 12; (24)Complexity: 135.

Preparation of Suberic acid: It can be obtained by cyclooctanone. This reaction needs reagent chromic acid and diluted sulfuric acid.

Uses of Suberic acid: It is used in plastics industry and polymer synthesis, It is also react with methanol to get octanedioic acid monomethyl ester. This reaction needs reagents water and HCl.

When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing and eye / face protection.

People can use the following data to convert to the molecule structure. 
1. SMILES:O=C(O)CCCCCCC(=O)O
2. InChI:InChI=1/C8H14O4/c9-7(10)5-3-1-2-4-6-8(11)12/h1-6H2,(H,9,10)(H,11,12) 
3. InChIKey:TYFQFVWCELRYAO-UHFFFAOYAN