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52829-07-9

Basic Information
CAS No.: 52829-07-9
Name: Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate
Article Data: 21
Molecular Structure:
Molecular Structure of 52829-07-9 (Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate)
Formula: C28H52N2O4
Molecular Weight: 480.732
Synonyms: Decanedioicacid, bis(2,2,6,6-tetramethyl-4-piperidinyl) ester (9CI);770DF;ADK Stab LA 77;ADK Stab LA 77Y;Adeka LA 77;BLS 1770;Bis(2,2,6,6-tetramethyl-4-piperidyl) decanedioate;HA 7OG;HALS 770;HS 770;Hillite 77;JF 90;LA 77;LA 77Y;LS 770;Lowilite 77;Mark LA 77;NF 90;Sanol 770;Sanol LS 770;Sumisorb 577;T770;TIN 770;Tinuvin 770DF1;Tinuvin770LS;Viosorb 04;
EINECS: 258-207-9
Density: 1.01 g/cm3
Melting Point: 82-85 °C(lit.)
Boiling Point: 590.214 °C at 760 mmHg
Flash Point: 310.75 °C
Solubility: acetone: 19 % (w/w) at 20 °C
Appearance: slightly yellowish crystalline granules
Hazard Symbols: ToxicT
Risk Codes: 23-37/38-41
Safety: 26-39-45
Transport Information: UN 2811 6.1/PG 2
PSA: 76.66000
LogP: 6.46960
Synthetic route
2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

Conditions
ConditionsYield
With ethanethiol In benzene17%
138847-20-8

2C44H56O4*C28H52N2O4

A

157432-87-6, 288302-11-4, 288302-12-5

5,11,17,23-tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene

B

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

Conditions
ConditionsYield
In acetonitrile at 25℃; Equilibrium constant;
2403-88-5

4-hydroxy-2,2,6,6-tetramethylpiperidine

106-79-6

dimethyl sebacate

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one
With 1-methyl-pyrrolidin-2-one
With sodium methylate In octane at 110 - 120℃; Large scale;
2403-88-5

4-hydroxy-2,2,6,6-tetramethylpiperidine

111-20-6

1,10-decanedioic acid

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

Conditions
ConditionsYield
With tetrabutoxytitanium at 220℃; under 760.051 Torr; for 10h; Temperature; Time; Inert atmosphere;
111-65-9

octane

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate

Conditions
ConditionsYield
Stage #1: octane; bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate With molybdenum trioxide at 130℃; Large scale;
Stage #2: With tert.-butylhydroperoxide at 90 - 130℃; for 10h; Temperature; Reagent/catalyst; Large scale;
96%
Stage #1: bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate With magnesium(II) chloride hexahydrate; dihydrogen peroxide In ethanol at 75℃; for 10h;
Stage #2: octane With tert.-butylhydroperoxide; molybdenum(VI) oxide at 125℃; for 3h; Reagent/catalyst; Reflux;
64.1%
With tert.-butylhydroperoxide; molybdenum(VI) oxide at 105 - 115℃; Large scale;
52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

123-72-8

butyraldehyde

C36H68N2O6

Conditions
ConditionsYield
Stage #1: bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate With tin (II) sulfate; dihydrogen peroxide In water at 20 - 25℃; for 24h;
Stage #2: butyraldehyde With dihydrogen peroxide; acetic acid; iron(II) chloride In ethanol at 225℃; for 8h;
Stage #3: With dihydrogen peroxide In ethanol at 25℃; for 24h;
89.02%
110-82-7

cyclohexane

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

bis(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate

Conditions
ConditionsYield
Stage #1: bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate With tin (II) sulfate; dihydrogen peroxide In water at 20 - 25℃; for 24h; Inert atmosphere;
Stage #2: cyclohexane With tetrabutylammomium bromide; dihydrogen peroxide; copper(II) sulfate In acetonitrile at 65℃; for 9.5h; Inert atmosphere;
83.67%
122-60-1

Phenyl glycidyl ether

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

155302-45-7

di[2,2,6,6-tetramethyl-1-(2-hydroxy-3-phenoxypropyl)-4-piperidyl] sebacate

Conditions
ConditionsYield
With sodium hydrogencarbonate81%
52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

131807-04-0

1-octyloxy-2,2,6,6-tetramethyl-4-hydroxy-piperidine

Conditions
ConditionsYield
With ethanol; potassium hydroxide at 70℃; for 3.5h;80.8%
aqueous tert-butyl hydroperoxide

aqueous tert-butyl hydroperoxide

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate

Conditions
ConditionsYield
In octane80%
With sodium sulfite; hexacarbonyl molybdenum In octane; water; ethyl acetate67%
In octane67%
Downstream Products
2516-92-9
111672-34-5
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    Product Description Product Name Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate CAS No. 52829-07-9 Appearance white crystal powder Assay ≥99% Capacity 500mt/year

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  • CAS: 52829-07-9 Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate

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    CAS: 52829-07-9 Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate

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  • 52829-07-9 Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate

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    52829-07-9 Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate

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Chemistry

IUPAC Name: Bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate
Synonyms of Decanedioic acid,1,10-bis(2,2,6,6-tetramethyl-4-piperidinyl) ester (CAS NO.52829-07-9):  ADK Stab LA 77 ; Bis(2,2,6,6-tetramethyl-4-piperidinyl) decanedioate ; Bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate ; Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate ; EINECS 258-207-9 ; HALS 1 ; HALS 770 ; LS 770 ; Mark LA 77 ; Sanol ; Sanol 770 ; Sanol LS 700 ; Sanol LS 770 ; Sumisorb 577 ; T 770 ; TIN 770 ; TK-10665 ; Tinuvin 770 ; Tinuvin 770DF ; Tinuvin 770LS ; Decanedioic acid, bis(2,2,6,6-tetramethyl-4-piperidinyl) ester
CAS NO: 52829-07-9
Molecular Formula of Decanedioic acid,1,10-bis(2,2,6,6-tetramethyl-4-piperidinyl) ester (CAS NO.52829-07-9): C28H52N2O4
Molecular Weight: 480.7235
Molecular Structure:

Melting Point: 82-85 °C
ProductCategories: Industrial/Fine Chemicals ; Polymer Additives ; Polymer Science ; Stabilizers 
Polar Surface Area: 59.08 Å2
Index of Refraction: 1.497
Molar Refractivity: 138.61 cm3
Molar Volume: 472.9 cm3
Surface Tension: 38.9 dyne/cm
Density of Decanedioic acid,1,10-bis(2,2,6,6-tetramethyl-4-piperidinyl) ester (CAS NO.52829-07-9): 1.01 g/cm3
Flash Point: 256 °C
Enthalpy of Vaporization: 76.82 kJ/mol
Boiling Point: 499.8 °C at 760 mmHg
Vapour Pressure: 4.03E-10 mmHg at 25°C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LC50 inhalation 500mg/m3/4H (500mg/m3) BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
National Technical Information Service. Vol. OTS0539874,

Safety Profile

Hazard Codes: ToxicT
Risk Statements: 23-37/38-41 
R23: Toxic by inhalation. 
R37/38: Irritating to respiratory system and skin. 
R41: Risk of serious damage to the eyes.
Safety Statements: 26-39-45 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S39: Wear eye / face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2811 6.1/PG 2
WGK Germany: 2
RTECS: HD8315000

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