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62610-77-9

Basic Information
CAS No.: 62610-77-9
Name: METHACRIFOS
Molecular Structure:
Molecular Structure of 62610-77-9 (METHACRIFOS)
Formula: C7H13O5PS
Molecular Weight: 240.23
Synonyms: Methacrifos;methyl (2E)-3-[(dimethoxyphosphinothioyl)oxy]-2-methyl-2-propenoate;methyl (E)-3-dimethoxyphosphinothioyloxy-2-methylprop-2-enoate;OMS-2005;Methacrifos (trans);methyl (2E)-3-[(dimethoxyphosphorothioyl)oxy]-2-methylprop-2-enoate;Methacrifos [ISO];2-Propenoic acid,3-((dimethoxyphosphinothioyl)oxy)-2-methyl-,methyl ester,(E);(E)-O-2-methoxycarbonylprop-1-enyl O,O-dimethyl phosphorothioate;trans-Methacrifos;Methyl (E)-3-(dimethoxyphosphinothioyloxy)-2-methylacrylate;
Density: 1.250±0.06 g/cm3(Predicted)
Melting Point: <25℃
Boiling Point: 258.9°C at 760 mmHg
Flash Point: 110.4°C
Hazard Symbols: Xn,N
Risk Codes: R22; R43; R50/53
Safety: Moderately toxic by ingestion inhalation, and skin contact. When heated to decomposition it emits toxic vapors of POx and SOx.
PSA: 95.89000
LogP: 2.24770
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Chemistry

IUPAC Name: Methyl (E)-3-dimethoxyphosphinothioyloxy-2-methylprop-2-enoate 
Molecular Formula: C7H13O5PS
Molecular Weight: 240.23
EINECS: 250-366-2
Properties: acaricide, pesticide.
Density: 1.25 g/cm3
Boiling Point: 258.3 °C at 760 mmHg 
Flash Point: 110 °C
Freely Rotating Bonds: 6
Polar Surface Area: 95.89Å2
Index of Refraction: 1.489
Molar Refractivity: 55.52 cm3
Molar Volume: 192 cm3
Polarizability: 22.01 ×10-24 cm3
Surface Tension: 42.8 dyne/cm
Enthalpy of Vaporization: 49.59 kJ/mol
Vapour Pressure: 0.0138 mmHg at 25°C
The Cas Register Number  of trans-Methacrifos  is 62610-77-9.The chemical synonyms of trans-Methacrifos  (CAS NO.62610-77-9) are (2E)-3-[(Diméthoxyphosphorothioyl)oxy]-2-méthylacrylate de méthyle ; (E)-3-[(Dimethoxyphosphinothioyl)oxy]-2-methyl-2-propenoic acid methyl ester ; (E)-O-2-Methoxycarbonylprop-1-enyl O,O-dimethyl phosphorothioate ; 2-Propenoic acid, 3-((dimethoxyphosphinothioyl)oxy)-2-methyl-, methyl ester, (E)- ; 2-Propenoic acid, 3-[(dimethoxyphosphinothioyl)oxy]-2-methyl-, methyl ester, (2E)- ; 3-((Dimethoxyphosphinothioyl)oxy)-2-methyl-2-propenoic acid methyl ester, (E)- ; Damfin ; Damfine ; Damphine ; Metacriphos ; Methyl (2E)-3-[(dimethoxyphosphorothioyl)oxy]-2-methylacrylate ; Methyl (E)-3-(dimethoxyphosphinothioyloxy)-2-methylacrylate ; Methyl (E)-3-hydroxy-2-methylacrylate O-ester with O,O-dimethyl phosphorothioate (8CI) ; Methyl 3-[(dimethoxyphosphinothioyl)oxy]methacrylate ; trans-Methacrifos  .Product categories of trans-Methacrifos  (CAS NO.62610-77-9) are  Acaricides Pesticides and Metabolites ; Alpha sort ; H-MAlphabetic ; Insecticides ; M ; Meta - meth Pesticides ; Organophorous ; Pesticides ; Pesticides and Metabolites .The molecular structure of trans-Methacrifos  (CAS NO.62610-77-9) is.

Uses

 trans-Methacrifos (CAS NO.62610-77-9) is used as pesticide .

Toxicity Data With Reference

1.    

orl-rat LD50:678 mg/kg

    PBCDDQ    Proceedings-British Crop Protection Conference-Pests and Diseases .(British Crop., Protection Council,Croydon, UK.: )1977,1033.
2.    

ihl-rat LC50:>2200 mg/m3/4H

    PBCDDQ    Proceedings-British Crop Protection Conference-Pests and Diseases .(British Crop., Protection Council,Croydon, UK.: )1977,1033.
3.    

skn-rat LD50:>3100 mg/kg

    PEMNDP    Pesticide Manual. 9 (1991),562.

Safety Profile

Moderately toxic by ingestion inhalation, and skin contact. When heated to decomposition it emits toxic vapors of POx and SOx.
Hazard Codes: HarmfulXn,DangerousN
Risk Statements: 22-43-50/53
R22: Harmful if swallowed.
R43: May cause sensitization by skin contact. 
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 36/37-60-61 
S36/37: Wear suitable protective clothing and gloves. 
S60: This material and its container must be disposed of as hazardous waste. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN3077 9/PG 3 
RTECS: UD3335000