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CAS No.: | 786-19-6 |
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Name: | CARBOPHENOTHION |
Article Data: | 5 |
Molecular Structure: | |
Formula: | C11H16 Cl O2 P S3 |
Molecular Weight: | 342.872 |
Synonyms: | Phosphorodithioicacid, S-[[(p-chlorophenyl)thio]methyl] O,O-diethyl ester (6CI,8CI); Acarithion;Carbofenothion; Carbofenotion; Carbofenthion; Carbophenothion; ENT 23,708;Ethyl carbophenothion; Garrathion; Hexathion; NSC 231691; O,O-DiethylS-(p-chlorophenylthio)methyl phosphorodithioate; Oleoakarithion; R 1303; R 1303(pesticide); S-[[(p-Chlorophenyl)thio]methyl] O,O-diethyl phosphorodithioate;Stauffer R 1303; Trithion |
Density: | 1.29(20oC) |
Melting Point: | 25°C |
Boiling Point: | 82(0.013kPa) |
Flash Point: | -18°C |
Solubility: | 630.2ug/L(20 oC) |
Appearance: | clear colorless liquid |
Hazard Symbols: | T,N,Xn,F |
Risk Codes: | 24/25-50/53-67-65-38-11-28-24 |
Safety: | Poison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by subcutaneous route. Mutation data reported. A cholinesterase inhibitor. When heated to decomposition it emits very toxic fumes of SOx, POx, and Cl−. See also PARATHION, ESTERS, and MERCAPTANS. |
PSA: | 110.96000 |
LogP: | 6.07090 |
IUPAC Name: (4-Chlorophenyl)sulfanylmethylsulfanyl-diethoxy-sulfanylidene-λ5-phosphane
Molecular Formula: C11H16ClO2PS3
Molecular Weight: 342.87
Transport information: 3018
Density: 1.32 g/cm3
Boiling Point: 398.4 °C at 760 mmHg
Flash Point: 194.7 °C
Properties: Amber liquid.
Solubility: essentially insol in water; misc in common solvents.
Freely Rotating Bonds: 8
Polar Surface Area: 110.96 Å2
Index of Refraction: 1.598
Molar Refractivity: 87.97 cm3
Molar Volume: 257.8 cm3
Polarizability: 34.87× 10-24 cm3
Surface Tension: 54.1 dyne/cm
Enthalpy of Vaporization: 62.36 kJ/mol
Vapour Pressure: 3.41E-06 mmHg at 25°C
The Cas Register Number of Trithion is 786-19-6.The chemical synonyms of Trithion (CAS NO.786-19-6) are R-1303;Phencapton(r) ; Phenacapton(r) ; O,O-Diethyl-s-[p-chlorophenylthio]-methyl phosphorodithioate ; S([(p-chlorophenyl)thio]methyl)-o,o-diethylphosphorodithioate ; S-(4-Chlorophenylthiomethyl) ,O-diethyl phosphorodithioate ; S-[(4-Chlorophenylthio)methyl]-o,o-diethyl phosphorodithionate ; Trithion .Product categories of Trithion (CAS NO.786-19-6) are AcaricidesAlphabetic ; C ; CA - CGPesticides ; Insecticides ; Organophorous ; Pesticides ; Pesticides and Metabolites .The molecular structure of Trithion (CAS NO.786-19-6) is .
It is used as an insecticide and acaricide, primarily for citrus crops and deciduous fruits and nuts.
Its raw materials are Iron ; Chlorosulfonic acid ; Phosphorus pentasulfide ; Dimethyl sulfide ; Petroleum crude oil ; 4-Chlorothiophenol ; 4-Chlorobenzenesulfonyl chloride .
1. | sce-hmn:lym 20 µg/L | MUREAV Mutation Research. 102 (1982),89. | ||
2. | orl-rat LD50:6800 µg/kg | FMCHA2 Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1983,C246. | ||
3. | skn-rat LD50:27 mg/kg | TXAPA9 Toxicology and Applied Pharmacology. 2 (1960),88. | ||
4. | ipr-rat LD50:6 mg/kg | APCRAW Advances in Pest Control Research. 4 (1961),117. | ||
5. | orl-mus LD50:218 mg/kg | ARSIM* Agricultural Research Service, USDA Information Memorandum. 20 (1966),6. | ||
6. | ipr-mus LD50:27 mg/kg | PSEBAA Proceedings of the Society for Experimental Biology and Medicine. 129 (1968),699. | ||
7. | orl-rbt LD50:1250 mg/kg | SPEADM Special Publication of the Entomological Society of America. 78-1 (1978),40. | ||
8. | skn-rbt LD50:1270 mg/kg | PCOC** Pesticide Chemicals Official Compendium ,Association of the American Pesticide Control Officials, Inc.(Topeka, KS.: )1966,200. | ||
9. | orl-ckn LD50:57 mg/kg | TXAPA9 Toxicology and Applied Pharmacology. 11 (1967),49. | ||
10. | scu-ckn LD50:640 mg/kg | BCPCA6 & |
EPA Farm Worker Field Reentry FEREAC Federal Register. 39 (1974),16888. . EPA Extremely Hazardous Substances List.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. Poison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by subcutaneous route. Mutation data reported. A cholinesterase inhibitor. When heated to decomposition it emits very toxic fumes of SOx, POx, and Cl−. See also PARATHION, ESTERS, and MERCAPTANS.
Hazard Codes: T,N,Xn,F
Risk Statements: 24/25-50/53-67-65-38-11
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65: Harmful: may cause lung damage if swallowed.
R67: Vapours may cause drowsiness and dizziness.
R38: Irritating to skin. R11:Highly flammable.
Safety Statements: 28-36/37-45-60-61-62
S28: After contact with skin, wash immediately with plenty of soap-suds.
S36/37: Wear suitable protective clothing and gloves.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60: This material and its container must be disposed of as hazardous waste.
Its extinguishing agent are sand, dry powder and foam.