Name: PHENYLMERCURIC NITRATE
SKU: 8003-05-2

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Basic Information

Molecular Structure:
CAS No.:	8003-05-2
Name:	PHENYLMERCURIC NITRATE

Formula:	C₆H₆HgO•C₆H₅HgNO₃
Molecular Weight:	634.42
Synonyms:	Gyne-merfen;phenylmercury nitrate hydrate;DZ;Mercury, hydroxyphenyl-, cmpd. with nitratophenylmercury (1:1);6509-33-7;Mercury, hydroxy(nitrato)diphenyldi-;Phenylmercuric nitrate, basic;Merfen-styli;Nitrate phenyl mercurique [French];Mercury, hydroxyphenyl-, mixt. with Phenylmercuric nitrate;Mercury nitratophenyl-, cmpd. with hydroxyphenylmercury (1:1);nitric acid; phenylmercury; hydrate;Phenylmercuric Nitrate (basic);MERCURY, HYDROXY-PHENYL-, cmpd. with NITRATOPHENYLMERCURY (1:1);NITRATE PHENYL MERCURIQUE;MERPHENE;PHERMERNITE;PHEMERN-ITE;
EINECS:	200-242-9
Melting Point:	175-185 °C (dec.)(lit.)
Solubility:	slightly
Appearance:	White to pale yellow powder
Hazard Symbols:	Toxic by ingestion, inhalation, and skin absorption.
Risk Codes:	25-34-48/24/25-50/53
Safety:	Poison by intravenous and subcutaneous routes. When heated to decomposition it emits very toxic fumes of Hg and NO_x. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and NITRATES.
PSA:	75.28000
LogP:	1.72280

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Chemistry

IUPAC Name: Hydroxy-phenyl-mercury; nitrooxy-phenyl-mercury
Synonyms: Mercury, hydroxyphenyl-, mixt. with Phenylmercuric nitrate ; Phenylmercuric nitrate, basic ; Phenylmercury nitrate
CAS NO: 8003-05-2
Molecular Formula of Merphenyl nitrate (CAS NO.8003-05-2) : C₁₂H₁₁Hg₂NO₄
Molecular Weight of Merphenyl nitrate (CAS NO.8003-05-2) : 634.4
Molecular Structure of Merphenyl nitrate (CAS NO.8003-05-2) :
EINECS: 200-242-9
Mol File: 8003-05-2.mol
Merck : 14,7302
Melting point: 175-185 °C (dec.)(lit.)
Appearance: white flake crystal pearl.
Solubility: slightly soluble in alcohol, very slightly soluble in water, almost insoluble in ether can be slowly dissolved in glycerol.

Uses

Merphenyl nitrate (CAS NO.8003-05-2) is used as preservatives and contraceptive materials in the pharmaceutical industry.

Production

Raw materials: PHENYLMERCURIC ACETATE
Merphenyl nitrate (CAS NO.8003-05-2) can be obtained by the reaction of Mercuric phenyl acetate and Sodium nitrate .

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD50	intravenous	27mg/kg (27mg/kg)	Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939.
mouse	LD50	subcutaneous	45mg/kg (45mg/kg)	Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939.
rat	LD50	subcutaneous	56mg/kg (56mg/kg)	Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939.

Consensus Reports

Mercury and its compounds are on the Community Right-To-Know List.

Safety Profile

Poison by intravenous and subcutaneous routes. When heated to decomposition it emits very toxic fumes of Hg and NO_x. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and NITRATES.
Hazard Codes Toxic T, Dangerous N
Risk Statements 34-48/24/25-50/53
R:48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R34:Causes burns.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 23-24/25-37-45-60-61
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.
S37:Wear suitable gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 1895 6.1/PG 2
WGK Germany 3
RTECS OW8575000
HazardClass 6.1
PackingGroup II

Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m³ (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m³ (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m³ (skin)