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887919-35-9

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Basic Information
CAS No.: 887919-35-9
Name: BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II)
Article Data: 2
Molecular Structure:
Molecular Structure of 887919-35-9 (BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II))
Formula: C32H56 Cl2 N2 P2 Pd
Molecular Weight: 708.084
Synonyms: BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);(A-taPhos)2PdCl2
Boiling Point: 349.1ºC at 760 mmHg
Flash Point: 164.9ºC
Solubility: Insoluble in water.
Hazard Symbols:
Risk Codes: 36/37/38
Safety:
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
PSA: 33.66000
LogP: 10.29260
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Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 16h; Solvent; Inert atmosphere;97%
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Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 9.5h; Inert atmosphere;1445 g
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Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: copper chloride / 0.17 h / -30 °C / Inert atmosphere
1.2: 0.5 h / -30 °C
2.1: tetrahydrofuran / 9.5 h / 20 °C / Inert atmosphere
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bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: copper bromide / 0.13 h / -60 °C / Inert atmosphere
1.2: 0.5 h / -60 °C
2.1: tetrahydrofuran / 9.5 h / 20 °C / Inert atmosphere
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Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: magnesium; iodine / tetrahydrofuran / 1 h / 50 - 60 °C / Inert atmosphere
2.1: copper chloride / 0.17 h / -30 °C / Inert atmosphere
2.2: 0.5 h / -30 °C
3.1: tetrahydrofuran / 9.5 h / 20 °C / Inert atmosphere
View Scheme
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4-bromo-N,N-dimethylaniline

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bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: magnesium; iodine / tetrahydrofuran / 1 h / 45 - 50 °C / Inert atmosphere
2.1: copper bromide / 0.13 h / -60 °C / Inert atmosphere
2.2: 0.5 h / -60 °C
3.1: tetrahydrofuran / 9.5 h / 20 °C / Inert atmosphere
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4-Iodo-N,N-dimethylaniline

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bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: magnesium; iodine / tetrahydrofuran / 1 h / 50 °C / Inert atmosphere
2.1: copper iodide / 0.2 h / 0 °C / Inert atmosphere
2.2: 0.5 h / -60 °C
3.1: tetrahydrofuran / 9.5 h / 20 °C / Inert atmosphere
View Scheme
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Conditions
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...Expand
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Conditions
ConditionsYield
With potassium carbonate87%
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  • Casno:

    887919-35-9

    Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladiuM(II)

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

    Hangzhou Dingyan Chem Co., LTD. is located in the beautiful tourist city of hangzhou, is a comprehensive chemical enterprice which doing import and export business by its own comp

  •  Hangzhou Dingyan Chem Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:86-571-86465881,86-571-87157530,86-571-88025800

    Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

       Inquiry Now

  • 887919-35-9

  • Casno:

    887919-35-9

    887919-35-9

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

    Wuxi TAA Chemical Industry Co.,Ltd., established in 2010, is a key chemical manufacturer and supplier in China. In 2010, three young chemists from a local large state-owned chemi

  •  Wuxi TAA Chemical Industry Co.,LTD.

     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:18168326835

    Address:2202 Scientific Research Business Center, Lihu Road, Wuxi 214128 China

       Inquiry Now

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