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89-02-1

Basic Information
CAS No.: 89-02-1
Name: 2,4-DINITROBENZENESULFONIC ACID
Article Data: 9
Molecular Structure:
Molecular Structure of 89-02-1 (2,4-DINITROBENZENESULFONIC ACID)
Formula: C6H4 N2 O7 S
Molecular Weight: 248.173
Synonyms: 2,4-Dinitrobenzenesulfonicacid; NSC 152110; NSC 163960
Density: 1.745 (estimate)
Melting Point: 95-98 °C(lit.)
Solubility: Soluble in methanol (2.5% w/v), slightly soluble in water.
Appearance: YELLOW TO YELLOW-BROWN CRYSTALLINE POWDER
Hazard Symbols:
Risk Codes: 34
Safety: Poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits very toxic fumes of NOx and SOx.
PSA: 154.39000
LogP: 2.87690
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Chemistry

Empirical Formula: C6H4N2O7S
Molecular Weight: 248.1702
EINECS: 201-876-9 
Melting point: 95-98 °C(lit.)
Index of Refraction: 1.643
Density: 1.826 g/cm3
Structure of 2,4-Dinitrobenzenesulfonic acid (CAS NO.89-02-1):
                           
IUPAC Name: 2,4-Dinitrobenzenesulfonic acid
Product Categories: Intermediates of Dyes and Pigments;Organic Building Blocks;Sulfonic/Sulfinic Acids

Uses

 2,4-Dinitrobenzenesulfonic acid (CAS NO.89-02-1) has been used for dye intermediate.

Production

 2,4-Dinitrobenzenesulfonic acid (CAS NO.89-02-1) can be derived by sulfonation from 2,4 - Dinitrochlorobenzene . Take 1100L water into the sulfonation pot, and has it heated to 50 °C, then keep stirring fast when join 119kg light Magnesium oxide . Stirring a moment then add 750kg melt: 2,4 - Dinitrochlorobenzene , and heated to 65 °C, add 462kg weight Sodium sulfite solution (dubbed 4.5-5N concentration) in 4h. At last, when the reaction is completed, has them beng cooled to 55 °C. Adding Hydrochloric acid , then add 35kg salt, cooled to 20 °C, put it aside, filtering, then we will get the product.

Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MOD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,180.
2.    

eye-rbt 500 mg/24H MLD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,180.
3.    

ivn-mus LD50:320 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#01550 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits very toxic fumes of NOx and SOx.
Hazard Codes: CorrosiveC
Risk Statements: 34 
R34:Causes burns.
Safety Statements: 26-36/37/39-45 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

Specification

 2,4-Dinitrobenzenesulfonic acid ,its cas register number is 89-02-1. It also can be called 2,4-Dinitrophenylsulfonic acid ;and Kyselina 2,4-dinitrobenzensulfonova .