CAS No.928-96-1,Leaf alcohol Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	928-96-1
Name:	Leaf alcohol
Article Data:	85

Formula:	C₆H₁₂O
Molecular Weight:	100.161
Synonyms:	3-Hexen-1-ol,(Z)- (8CI);3-Hexen-1-ol, cis- (5CI);(3Z)-3-Hexen-1-ol;(3Z)-Hexenol;(Z)-3-Hexen-1-ol;(Z)-3-Hexenol;(Z)-Hex-3-en-1-ol;3Z-Hexen-1-ol;Blaetteralkohol;ENT 25091;Folic alcohol;Green leaf alcohol;cis-3-Hexen-1-ol;cis-3-Hexene-1-ol;cis-3-Hexenol;
EINECS:	213-192-8
Density:	0.843 g/cm³
Melting Point:	-60oC
Boiling Point:	156.5 °C at 760 mmHg
Flash Point:	44.4 °C
Solubility:	insoluble in water
Appearance:	colourless liquid
Hazard Symbols:	F
Risk Codes:	10
Safety:	16
Transport Information:	UN 1987 3/PG 3
PSA:	20.23000
LogP:	1.33500

Synthetic route

: 1002-28-4
3-hexyn-1-ol

: 928-96-1
(Z)-3-Hexen-1-ol

Conditions

Conditions	Yield
With hydrogen; N,N′-bis(salicylidene)-ethylenediamino‑palladium In pyridine for 0.283333h;	100%
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760.051 Torr;	99%
With trichlorosilane; silica gel; acetic acid; tetrakis(triphenylphosphine) palladium(0) In dichloromethane for 3h; Ambient temperature;	96%

: 1002-28-4
3-hexyn-1-ol

A: 928-96-1
(Z)-3-Hexen-1-ol

B: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;	A 99% B n/a
With hydrogen In methanol at 30℃; under 760.051 Torr; for 3h;	A 99% B 1%
With hydrogen In methanol at 20℃; under 150.015 - 900.09 Torr; for 0.0116667h; Inert atmosphere; Schlenk technique; Green chemistry;	A n/a B n/a

: 111-28-4
2,4-hexadiene-1-ol

A: 928-96-1
(Z)-3-Hexen-1-ol

B: 928-97-2
(E)-3-hexen-1-ol

C: 6126-50-7, 928-91-6, 928-92-7
hex-4-en-1-ol

D: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With hydrogen; (methyl benzoate)Cr(CO)6 In methanol at 190 - 200℃; under 36775.4 Torr; for 2h;	A 92.5% B 4.6% C 2.3% D 0.6%
With hydrogen; (1,2,4,5-tetramethylbenzene)tricarbonylchromium(0) In methanol at 190 - 200℃; under 36775.4 Torr; for 4h; Product distribution; other arene ligands, other solvents; also in absence of arene ligands;

...Expand

: 1002-28-4
3-hexyn-1-ol

A: 928-96-1
(Z)-3-Hexen-1-ol

B: 928-97-2
(E)-3-hexen-1-ol

C: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With hydrogen In methanol at 20℃; under 1800.18 Torr; Catalytic behavior; Reagent/catalyst;	A 88% B n/a C n/a
With hydrogen; poly(N-vinyl-2-pyrrolidone)-stabilised Pd-nanoclusters In methanol at 29℃;
With hydrogen In isopropyl alcohol at 30℃; under 2250.23 Torr; for 20h; Autoclave; optical yield given as %de; stereoselective reaction;

...Expand

: 17102-64-6
Sorbyl alcohol

: 928-96-1
(Z)-3-Hexen-1-ol

Conditions

Conditions	Yield
With Na12(Ga4(1,5-bis(2,3-dihydroxybenzamido)naphthalene))6; [(DMPE)Rh(COD)][BF4]; hydrogen In water-d2 at 20℃; for 12h;	84%
With hydrogen; chromium(0) hexacarbonyl In hexane at 160 - 180℃; under 38000 - 60800 Torr; for 4h;
With hydrogen; [(η5-C5Me5)Ru(η4-MeCH=CHCH=CHCO2H)] triflate In ethylene glycol at 40℃; under 15001.5 Torr; for 0.42h; Catalytic hydrogenation;

: 6789-80-6
(3Z)-hexenal

: 928-96-1
(Z)-3-Hexen-1-ol

Conditions

Conditions	Yield
With 1% Rh/Al2O3; hydrogen; iron In ethanol at 120℃; under 15001.5 Torr; for 4h; Reagent/catalyst; Temperature; Pressure; Solvent; Autoclave;	80.35%
With aldehyde reductase; nicotinamide adenine dinucleotide phosphate Enzymatic reaction;

: 55230-25-6
6-methyl-3,6-dihydro-2H-pyran

: 928-96-1
(Z)-3-Hexen-1-ol

Conditions

Conditions	Yield
With calcium; ethylenediamine at 90℃; for 8h;	60%

: 627-27-0
homoalylic alcohol

: 96-10-6
diethylaluminium chloride

A: 589-35-5, 20281-83-8
3-methyl-1-pentanol

B: 928-96-1
(Z)-3-Hexen-1-ol

C: 928-97-2
(E)-3-hexen-1-ol

D: 71-36-3
butan-1-ol

E: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With titanium tetrachloride In dichloromethane at -45℃; for 2h; Mechanism; Product distribution; variation of added base;	A 13% B 3% C 18% D 20% E 21%

...Expand

: 1002-28-4
3-hexyn-1-ol

A: 928-96-1
(Z)-3-Hexen-1-ol

B: 928-97-2
(E)-3-hexen-1-ol

Conditions

Conditions	Yield
With Pd-BaSO4; benzene at 50℃; Hydrogenation;
With lithium; Trimethylenediamine at 25℃; for 2h;
With palladium/highly-ordered mesoporous silica supported 3-D pore network(3.7) 1-phenylethan-1-amine 0.02 for 2.91667h;
With hydrogen In methanol at 20℃; under 862.586 Torr; for 8h; Catalytic behavior; Flow reactor;	A n/a B n/a

: 98486-14-7
cis/trans-3-chloro-2-ethyltetrahydrofuran

A: 928-96-1
(Z)-3-Hexen-1-ol

B: 928-97-2
(E)-3-hexen-1-ol

Conditions

Conditions	Yield
With samarium diiodide In tetrahydrofuran Product distribution; Heating; using dipolar-aprotic cosolvents;
With samarium diiodide In tetrahydrofuran for 5h; Heating; Yield given. Yields of byproduct given;

Raw Materials

71-43-2

1002-28-4

60-29-7

142-83-6

55230-25-6

109-67-1

111-28-4

Downstream Products

928-97-2

488-10-8

Total:149 Page 1 of 4 1 2 3 4 Next>>

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Chemistry

IUPAC Name:(Z)-hex-3-en-1-ol
Molecular Formula:C₆H₁₂O
Molecular Weight:100.18
EINECS:213-192-8
Density:0.848g/mL at 25 °C(lit.)
Boiling Point:156-157 °C
Flash Point:44 °C
Water Solubility:Insoluble
Appearance:Colourless liquid
cis-3-HEXENOL's(928-96-1) Synonyms: (3Z)-3-Hexen-1-ol;(z)-3-hexen-1-o;(Z)-3-Hexen-1-ol;(Z)-Hex-3-en-1-ol;(Z)-Hex-3-ene-1-ol;(Z)Hex-3-enol;1-Hydroxyhex-3-ene;3-(Z)-Hexenol
cis-3-HEXENOL's(928-96-1) Molecular Structure:

Toxicity Data With Reference

1.	orl-rat LD50:4700 mg/kg	FCTXAV Food and Cosmetics Toxicology. 12 (1974),909.
2.	ipr-rat LD50:600 mg/kg	FCTXAV Food and Cosmetics Toxicology. 7 (1969),451.
3.	orl-mus LD50:7000 mg/kg	FCTXAV Food and Cosmetics Toxicology. 7 (1969),451.
4.	ipr-mus LD50:400 mg/kg	FCTXAV Food and Cosmetics Toxicology. 7 (1969),451.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison by intraperitoneal route. Mildly toxic by ingestion. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..

Safety Information of cis-3-HEXENOL(928-96-1)
Hazard Codes F
Risk Statements 10
Safety Statements 16
RIDADR UN 1987 3/PG 3
WGK Germany 1
RTECS MP8400000
F 10
HazardClass 3
PackingGroup III
HS Code 29052990