100191-13-7

Basic information

• Product Name: (1R,2R,4S,5S)-6,7-Diaza-tricyclo[3.2.2.0^2,4]non-8-ene-6,7-dicarboxylic acid diethyl ester
• Synonyms: (1R,2R,4S,5S)-6,7-Diaza-tricyclo[3.2.2.0^2,4]non-8-ene-6,7-dicarboxylic acid diethyl ester
• CAS NO: 100191-13-7
• Molecular Weight: 266.297
• Mol File: 100191-13-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2R,4S,5S)-6,7-Diaza-tricyclo[3.2.2.0^2,4]non-8-ene-6,7-dicarboxylic acid diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,4S,5S)-6,7-Diaza-tricyclo[3.2.2.0^2,4]non-8-ene-6,7-dicarboxylic acid diethyl ester(100191-13-7)
• EPA Substance Registry System: (1R,2R,4S,5S)-6,7-Diaza-tricyclo[3.2.2.0^2,4]non-8-ene-6,7-dicarboxylic acid diethyl ester(100191-13-7)

Safety Data

• Hazardous Substances Data: 100191-13-7(Hazardous Substances Data)

Upstream product

• 4143-61-7 diethyl diazodicarboxylate 
• 544-25-2 Cyclohepta-1,3,5-triene 

Relevant articles and documents

High-Pressure Addition Reactions Involving Cycloheptatriene-Norcaradiene Equilibrium

Several high-pressure reactions of cycloheptatriene (CHT) were investigated with various unsaturated compounds.With homonuclear bonds (C=C,CC, N=N),norcaradiene adducts were formed, whereas with the unsymmetrical C=O bond, only ene-type addition was observed.There is a general tendency to form norcaradiene adducts under high pressure (reactions of CHT with acrylonitrile and acetylenic bonds).Several unprecedented peculiar features are observed under pressure: inter- and intramolecular formation of the norcaradiene adduct (CHT-dimethyl acetylenedicarboxylate),homo Diels-Alder reactions involving bicyclooctadiene systems (CHT-methylpropiolate), formation of the unknown norcaradiene adduct with the N-N fragment (CHT-diethyl azodicarboxylate) showing interesting NMR properties reflecting conformational changes.