100337-62-0Relevant articles and documents
Metal-free Mizoroki-Heck type reaction: A radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins
Du, Wenbin,Lai, Junshan,Tian, Lixia,Xie, Xingang,She, Xuegong,Tang, Shouchu
, p. 14017 - 14020 (2014)
An efficient metal-free Mizoroki-Heck type reaction of di- and tri-substituted alkenes with 2-chloro-dithiane has been developed under ambient pressure of air or using a relatively low loading of BF3·Et2O. This study represents a new environmentally friendly method for the syntheses of dithianyl-substituted alkene derivatives via a radical oxidative coupling process.
Efficient synthesis of polysubstituted olefins using stable palladium nanocatalyst: Applications in synthesis of tamoxifen and isocombretastatin A4
Ganapathy, Dhandapani,Sekar, Govindasamy
supporting information, p. 3856 - 3859 (2014/08/18)
A phosphine-free stable palladium nanocatalyst was used for an efficient synthesis of polysubstituted olefins from N-tosylhydrazones and aryl iodides. This methodology was successfully utilized in the synthesis of biologically important tamoxifen and isocombretastatin A4. The nanocatalyst was easily recovered and reused without any apparent loss in size and catalytic activity.
Friedel-Crafts alkenylation of arenes using alkynes catalysed by metal trifluoromethanesulfonates
Tsuchimoto,Maeda,Shirakawa,Kawakami
, p. 1573 - 1574 (2007/10/03)
Metal trifluoromethanesulfonates [M(OTf)(n); M = Sc, Zr, In] catalyse the Friedel-Crafts alkenylation of arenes using alkynes, including internal alkynes, to give, through an alkenyl cation intermediate, 1,1-diarylalkenes in high to excellent yields.