1004-55-3

Basic information

• Product Name: Ethanone, 1-(1-chlorocyclohexyl)-
• CAS NO: 1004-55-3
• Molecular Formula: C8H13ClO
• Molecular Weight: 160.644
• Mol File: 1004-55-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(1-chlorocyclohexyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(1-chlorocyclohexyl)-(1004-55-3)
• EPA Substance Registry System: Ethanone, 1-(1-chlorocyclohexyl)-(1004-55-3)

Safety Data

• Hazardous Substances Data: 1004-55-3(Hazardous Substances Data)

Usage

General Description

Ethanone, 1-(1-chlorocyclohexyl)- is a chemical compound that belongs to the ketone group, containing a cyclohexyl ring with a chlorine atom attached at the first carbon position. Ethanone, 1-(1-chlorocyclohexyl)- is commonly used in organic synthesis as a building block in the production of various pharmaceuticals and agrochemicals. It is also used as a solvent for various chemical reactions due to its high solubility in a wide range of organic solvents. Additionally, it has applications in the fragrance industry, where it is utilized as a key ingredient in the manufacture of perfumes and other scented products. Overall, Ethanone, 1-(1-chlorocyclohexyl)- is a versatile compound with diverse uses in different industrial sectors.

Upstream product

• 98959-54-7 2-methyl-1-oxaspiro[2.5]octane-2-carbonitrile 
• 54683-51-1 1-methyl-2-methylenecyclohexyl hydroperoxide 
• 26473-57-4 (1-methoxyethylidene)cyclohexane 
• 98841-10-2 2-Hydroxy-2-<1-Chlor-cyclohexyl-(1)>-propionitril 
• 823-76-7 Cyclohexyl methyl ketone 
• 1674-10-8 1,2-dimethylcyclohexene 

Downstream Products

• 1123-26-8 1-(1'-hydroxyethyl)-1-cyclohexanol 
• 927386-32-1 (R_S,R)-N-(1-phenylspiro[2.5]oct-1-yl)-tert-butanesulfinamide 
• 927386-24-1 (R_S)-(-)-N-[1-(1-chlorocyclohexyl)ethylidene]-tert-butanesulfinamide 
• 1123-27-9 1-(1-hydroxycyclohexyl)ethan-1-one 
• 1756-33-8 1-cyclohex-1-enyl-ethanone-(2,4-dinitro-phenylhydrazone) 
• 1123-25-7 1-methyl-1-cyclohexanecarboxylic acid 
• 7499-13-0 <1-Semicarbazo-ethyl-(1)>-cyclohexen-(1) 
• 64639-28-7 (1-trimethylsiloxyethylidene)cyclohexane 
• 932-66-1 1-cyclohexenyl methyl ketone 
• 40702-53-2 1-(1-amino-cyclohexyl)-ethanone 
• 1209-42-3 1-methyl-cyclohexanecarboxylic acid phenyl ester 

Relevant articles and documents

Regioselective radical cyclization initiated by the reaction of allylic hydroperoxides with iron(II) sulfate

Treatment of 1-methyl-2-methylene-1-cyclohexyl hydroperoxide with a mixture of FeSO4/CuCl2 yielded 1-(1-chlorocyclohexyl)ethanone as the major product consistent with 6-endo-trig cyclization of the intermediate 5-acetylhex-5-enyl rad

The photochemical addition of N-haloamides to olefins: the influence of various factors on the competition between 1,2-addition and hydrogen abstraction

In the photodecomposition of N-haloamides (ZCONRX) in the presence of olefins, the 1,2-addition chain competes with the hydrogen abstraction chain(s) leading to the parent amide (the quantum yields for these processes are greater than unity).The following factors were shown to have an influence on this competition as measured by the yield of 1,2-addition and the yield of parent amide in methylene chloride solutions: (i) the N-halogen (higher yields of addition with X=Cl than with X=Br); (ii) the electronegativity of Z (increase of the yield of addition as the electronegativity of Z increases); (iii) the temperature (higher yields of addition at lower temperatures, and at -70 degC, better yields of addition (>90percent, R=H) for X=Br than for X=Cl); and (iv) the size of R (dramatic decrease of the yield of 1,2-addition in going from R=H to R=CH3).Surprisingly, the presence of a scavenger for HX had no influence on the yield of 1,2-addition.Both the size and electronegativity of Z had an effect on the stereochemistry of 1,2-addition to cyclohexene.High yields of addition to a variety of olefins were obtained with N-chloroamides such as ClCH2CONHCl, C2H5OCONHCl, CF3CONHCl.Their addition to enol ethers at -70 degC led to the synthesis of α-amido acetals or ketals (aldehydes or ketones) and to an α-amido glycoside in good yields.