100709-31-7

Basic information

• Product Name: 1,2-Ethanediamine, N,N'-bis(4-bromophenyl)-
• CAS NO: 100709-31-7
• Molecular Formula: C14H14Br2N2
• Molecular Weight: 370.087
• Mol File: 100709-31-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2-Ethanediamine, N,N'-bis(4-bromophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Ethanediamine, N,N'-bis(4-bromophenyl)-(100709-31-7)
• EPA Substance Registry System: 1,2-Ethanediamine, N,N'-bis(4-bromophenyl)-(100709-31-7)

Safety Data

• Hazardous Substances Data: 100709-31-7(Hazardous Substances Data)

Upstream product

• 106-93-4 ethylene dibromide 
• 106-40-1 4-bromo-aniline 
• 150-61-8 N,N'-diphenylethylenediamine 
• 101102-79-8 formic acid-{4-bromo-N-[2-(4-bromo-anilino)-ethyl]-anilide} 
• 30881-03-9 N,N'-bis-(4-bromophenyl)formamidine 
• 21022-25-3 N¹,N²-bis(4-bromophenyl)oxalamide 

Downstream Products

• 101102-77-6 1,3-bis-(4-bromo-phenyl)-imidazolidine 
• 109495-43-4 1,3-bis-(4-bromo-phenyl)-4,5-dihydro-imidazolium; bromide 
• 854247-52-2 N,N'-bis-(2,4,6-tribromo-phenyl)-ethylenediamine 
• 70009-75-5 N,N'-bis-(2,4-dibromo-phenyl)-ethylenediamine 

Relevant articles and documents

A convenient one-pot synthesis of symmetric secondary and tertiary vicinal diamines

A convenient one-pot synthesis of symmetric vicinal diamines utilizing sodium borohydride/trifluoroacetic acid reduction methodology is described.

Catalyst-Free Synthesis of Aryl Diamines via a Three-Step Reaction Process

The formation of C-N bonds with aryl amines is one of the most widely studied reactions in organic chemistry. Despite this, it is still highly challenging, often requiring expensive, precious metal-based catalysts. Here we report an easy catalyst-free methodology for constructing C-N bonds. The method, which proceeds via the in situ formation of closed ring amidinium ions, allows the preparation of a series of symmetrical and/or unsymmetrical aryl diamines in notably high yields (82-98%) and purity and with a variety of different substituents. The methodology is shown successful for the preparation of aryl diamines having para- and/or meta-substituted carboxyl, nitro, bromo, methoxy, or methyl groups. This green synthetic pathway, which is catalyst free, requires only three steps, and proceeds without the need for purification. Further, it is a new sustainable, economically viable method to achieve an otherwise challenging bond formation.