1007090-75-6

Basic information

• Product Name: N-(4-nitrophenyl)-10,11-dihydro-10,11aza-cyclopropa-5H-dibenzo[a,d]cyclohepten-5-one
• CAS NO: 1007090-75-6
• Molecular Weight: 342.354
• Mol File: 1007090-75-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-nitrophenyl)-10,11-dihydro-10,11aza-cyclopropa-5H-dibenzo[a,d]cyclohepten-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-nitrophenyl)-10,11-dihydro-10,11aza-cyclopropa-5H-dibenzo[a,d]cyclohepten-5-one(1007090-75-6)
• EPA Substance Registry System: N-(4-nitrophenyl)-10,11-dihydro-10,11aza-cyclopropa-5H-dibenzo[a,d]cyclohepten-5-one(1007090-75-6)

Safety Data

• Hazardous Substances Data: 1007090-75-6(Hazardous Substances Data)

Upstream product

• 1516-60-5 4-nitrophenyl azide 
• 2222-33-5 dibenzosuberenon 

Relevant articles and documents

The (porphyrin)ruthenium-catalyzed aziridination of olefins using aryl azides as nitrogen sources

Aryl azides have been used as atom-efficient nitrene transfer reagents in the (porphyrin)ruthenium-catalyzed amination of olefins. Several azides, olefins and [Ru(porphyrin)CO] complexes were tested to investigate the scope and limits of the reaction. Quantitative yields and short reaction times were achieved by using terminal olefins and aryl azides bearing electron-withdrawing groups on the aryl moiety. The reactions were influenced by steric factors. Internally disubstituted olefins exhibited a lower reactivity and tri- and tetra-substituted olefins did not react at all. A very high turnover number (TON) for the [Ru(TPP)CO] (TPP = tetraphenylporphyrin dianion) catalyzed amination of α-methylstyrene by p-nitrophenyl azide was obtained. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.