1007362-95-9Relevant articles and documents
Synthesis of a tertiary carbinamide via a novel Rh-catalyzed asymmetric hydrogenation
Limanto, John,Shultz, C. Scott,Dorner, Benjamin,Desmond, Richard A.,Devine, Paul N.,Krska, Shane W.
, p. 1639 - 1642 (2008/09/17)
(Chemical Equation Presented) Asymmetric hydrogenation of allylic dimethylcarbinamide 2 with 1 mol % of cationic Rh(I)-Josiphos complex in THF under 500 psi of H2 generated the corresponding tertiary carbinamide 1 in 98.5% assay yield and a 94: