100758-38-1

Basic information

• Product Name: 2,3,3,4,5,6,6-heptafluoro-1-iodo-cyclohexa-1,4-diene
• CAS NO: 100758-38-1
• Molecular Weight: 331.959
• Mol File: 100758-38-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,3,3,4,5,6,6-heptafluoro-1-iodo-cyclohexa-1,4-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,3,4,5,6,6-heptafluoro-1-iodo-cyclohexa-1,4-diene(100758-38-1)
• EPA Substance Registry System: 2,3,3,4,5,6,6-heptafluoro-1-iodo-cyclohexa-1,4-diene(100758-38-1)

Safety Data

• Hazardous Substances Data: 100758-38-1(Hazardous Substances Data)

Upstream product

• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 

Relevant articles and documents

Regiospecific fluorination of the aryl group in C6F5I and the preparation of C6F7IF2 - The first perfluorovinyl iodine (III) compound

Pentafluoroiodobenzene was oxidized regiospecificly by IF5/BF3 in CH2C12 to 1-iodo-heptafluoro-1,4-cyclohexadiene. With bromo- and chloro-pentafluorobenzene as substrates, the addition of two fluorine atoms to the aromatic ring proceeded analogously but more slowly. 1-Iodo-heptafluoro-1,4-cyclohexadiene was converted to 1-difluoroiodo-heptafluoro-1,4-cyclohexadiene by low-temperature fluorination. The thermal stability and reactivity of the first example of a perfluorinated vinyl iodine(III) compound are reported.

FLUORINATION OF POLYFLUOROAROMATIC COMPOUNDS WITH VANADIUM PENTAFLUORIDE

Fluorination of polyfluoro-derivatives of benzene and diphenyl with vanadium pentafluoride at -25 to -10 deg C afforded fluorinated cyclohexadienes and cyclohexenes.Octafluoronaphthalene was converted under these conditions to perfluoro-1,4-dihydronaphthalene, perfluorotetralin, perfluoro-1,4,5,8-tetrahydronaphthalene and perfluoro-1,2,3,4,5,8-hexahydronaphthalene.