100798-11-6

Basic information

• Product Name: 1,2-INDANYL DIACETATE
• Synonyms: 1,2-INDANYL DIACETATE
• CAS NO: 100798-11-6
• Molecular Formula: C₁₃H₁₄O₄
• Molecular Weight: 234.25
• Mol File: 100798-11-6.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2-INDANYL DIACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-INDANYL DIACETATE(100798-11-6)
• EPA Substance Registry System: 1,2-INDANYL DIACETATE(100798-11-6)

Safety Data

• Hazardous Substances Data: 100798-11-6(Hazardous Substances Data)

Usage

Physical state

Colorless liquid

Odor

Sweet, fruity

Uses

a. Fragrance ingredient in perfumes and cosmetic products
b. Flavoring agent in food products

Synthesis

Derived from indene (an aromatic hydrocarbon) and acetic acid through an esterification reaction

Stability

Relatively stable under normal conditions

Reactivity

Can react violently with strong oxidizing agents

Classification

Flammable liquid

Hazards

a. Harmful if ingested
b. Harmful if inhaled
c. Harmful if absorbed through the skin

Upstream product

• 186581-53-3 diazomethane 
• 64-19-7 acetic acid 
• 95-13-6 1-indene 
• 4370-02-9 cis-indane-1,2-diol 
• 108-24-7 acetic anhydride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Relevant articles and documents

IODOSOBENZENE TETRAFLUOROBORATE: FIRST EXAMPLE OF A STABLE ELECTROPHILIC HYPERVALENT IODINE REAGENT WITHOUT NUCLEOPHILIC LIGANDS

Iodosobenzene tetrafluoroborate 1 has been prepared by the reaction of PhI(OAc2) and aqueous HBF4, and its reactions with alkenes, silyl enol ethers, and acetylenes have been studied.

Metal-free, organocatalytic syn diacetoxylation of alkenes

A novel method for the organocatalytic syn diacetoxylation of alkenes has been developed using aryl iodides as efficient catalysts. A broad range of substrates, including electron-rich as well as electron-deficient alkenes, are smoothly transformed by the new procedure, furnishing the desired products in good to excellent yields with high diastereoselectivity (up to >19:1 dr).

Bis(NHC)-palladium(II) complex-catalyzed dioxygenation of alkenes

Bis(NHC)-Pd(II) complexes derived from l,l'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex 1e showed the highest catalytic activity to give 1,2dioxygenation products with good syn-diastereoselectivity for 1,2-disubstituted alkenes.