100939-31-9

Basic information

• Product Name: methyl trans-2,3-epoxy-hexanoate
• Synonyms: methyl trans-2,3-epoxy-hexanoate
• CAS NO: 100939-31-9
• Molecular Weight: 144.17
• Mol File: 100939-31-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl trans-2,3-epoxy-hexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl trans-2,3-epoxy-hexanoate(100939-31-9)
• EPA Substance Registry System: methyl trans-2,3-epoxy-hexanoate(100939-31-9)

Safety Data

• Hazardous Substances Data: 100939-31-9(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 89395-00-6 2,3-epoxyhexan-1-ol 

Downstream Products

• 100946-31-4 α-(1-Hydroxybutyl)benzenessigsaeure-methylester 
• 21188-58-9 methyl 3-hydroxyhexanoate 
• 100992-83-4 (2R,3R)-2-Butyl-3-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-hexanoic acid methyl ester 
• 100939-37-5 (2S,3S)-2-Butyl-3-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-hexanoic acid methyl ester 

Relevant articles and documents

Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes.11. Ring opening reactions of aliphatic mono- and difunctionalized cis and trans 2,3- and 3,4-epoxy esters

The regiochemical outcome of the ring opening of 1,2-epoxides through chelation processes assisted by metal ions, was verified in the azidolysis of simple aliphatic cis and trans 2,3- and 3,4-epoxy esters and in the corresponding derivatives bearing an ether functionality (OBn) in an allylic relationship to the oxirane ring. The results indicate that the behavior of these epoxides is influenced both by the opening conditions (standard or metal-assisted) and the promoting metal salt [LiClO4 or Mg(ClO4)2]. Copyright