1010127-34-0

Basic information

• Product Name: (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane
• Synonyms: (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane
• CAS NO: 1010127-34-0
• Molecular Weight: 254.329
• Mol File: 1010127-34-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane(1010127-34-0)
• EPA Substance Registry System: (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane(1010127-34-0)

Safety Data

• Hazardous Substances Data: 1010127-34-0(Hazardous Substances Data)

Upstream product

• 944335-23-3 (2S)-4-[4-(benzyloxy)phenyl]-2-hydroxybutyl 4-methyl-1-benzenesulfonate 
• 61440-45-7 3-[4-(benzyloxy)phenyl]propan-1-ol 
• 134721-17-8 1-(benzyloxy)-4-(but-3-en-1-yl)benzene 
• 79407-40-2 2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane 
• 6272-45-3 4-benzyloxycinnamic acid 
• 100-39-0 benzyl bromide 
• 123-08-0 4-hydroxy-benzaldehyde 
• 944335-22-2 (2S)-4-[4-(benzyloxy)phenyl]butane-1,2-diol 
• 1638640-10-4 C₂₃H₂₅NO₃ 
• 69172-21-0 4-(4-Benzyloxyphenyl)butanal 
• 1166181-77-6 methyl 4-[4-(benzyloxy)phenyl]butanoate 
• 243641-03-4 C₁₈H₁₈O₃ 
• 186895-45-4 ethyl 3-(4-(benzyloxy)phenyl)propanoate 
• 87030-11-3 ethyl 3-(4-(benzyloxy)phenyl)acrylate 

Downstream Products

• 1010127-36-2 C₁₉H₂₀O₂ 
• 1401711-88-3 (3R)-1-[4-(benzyloxy)phenyl]hept-6-en-3-ol 
• 1251830-59-7 4,4'-[(1E,5R)-5-hydroxyhept-1-ene-1,7-diyl]diphenol 
• 1401711-90-7 4-{(1E,5R)-7-[4-(benzyloxy)phenyl]-5-hydroxyhept-1-en-1-yl}phenol 
• 1638640-04-6 ({(3S)-1-[4-(benzyloxy)phenyl]hex-5-en-3-yl}oxy)(tert-butyl)(dimethyl)silane 
• 1638640-11-5 C₂₅H₃₆O₃Si 
• 1258516-47-0 {(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane 
• 1443256-45-8 (3S,5R)-1-(4-hydroxyphenyl)nonadecane-3,5-diol 
• 767330-04-1 (-)-(3S)-1-[4-(benzyloxy)phenyl]hex-5-en-3-ol 

Relevant articles and documents

Catalytic δ-hydroxyalkynone rearrangement in the stereoselective total synthesis of centrolobine, engelheptanoxides A and C and analogues

A catalytic stereoselective total synthesis of centrolobine and engelheptanoxides A and C has been completed via a metal-free catalytic δ-hydroxyalkynone rearrangement to 2,3-dihydro-4H-pyran-4-one and diastereoselective hydrogenation to the all syn-2,4,6-trisubstituted pyran strategy. The onliest required chirality was introduced by Jacobsen kinetic resolution, which further directed the diastereoselective hydrogenation. A first stereoselective synthesis of engelheptanoxide A is also accomplished. The analogues and derivatives of centrolobine and engelheptanoxides prepared were evaluated for antitubercular activity against M. tuberculosis H37Rv ATCC 27294.

The first stereoselective total synthesis of a naturally occurring bioactive diarylheptanoid, (3R,6E)-1,7-bis(4-hydroxyphenyl)hept-6-en-3-ol, through two different approaches

The stereoselective total synthesis of a naturally occurring bioactive diarylheptanoid, (3R,6E)-1,7-bis(4-hydroxyphenyl)hept-6-en-3-ol, has been accomplished starting from 4-hydroxybenzaldehyde through two different approaches involving Wittig olefination