101069-28-7

Basic information

• Product Name: 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3-deoxy-3-C-(ethoxycarbonylmethyl)-5,6-O-isopropylidene-D-allitol
• CAS NO: 101069-28-7
• Molecular Weight: 512.718
• Mol File: 101069-28-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3-deoxy-3-C-(ethoxycarbonylmethyl)-5,6-O-isopropylidene-D-allitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3-deoxy-3-C-(ethoxycarbonylmethyl)-5,6-O-isopropylidene-D-allitol(101069-28-7)
• EPA Substance Registry System: 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3-deoxy-3-C-(ethoxycarbonylmethyl)-5,6-O-isopropylidene-D-allitol(101069-28-7)

Safety Data

• Hazardous Substances Data: 101069-28-7(Hazardous Substances Data)

Upstream product

• 7726-97-8 1,4-anhydro-D-glucitol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 55730-73-9 (2S,3R,4S)-2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-furan-3,4-diol 
• 101125-99-9 1,4-anhydro-2-O-tert-butyldiphenylsilyl-5,6-O-isopropylidene-D-ribo-3-hexulose 
• 101069-26-5 1,4-anhydro-2-O-tert-butyldiphenylsilyl-5,6-O-isopropylidene-D-glucitol 
• 101069-27-6 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3-deoxy-3-C-(ethoxycarbonylmethylene)-5,6-O-isopropylidene-D-ribo-hexitol 
• 55730-76-2 1,4:2,3-dianhydro-5,6-O-isopropylidene-D-mannitol 
• 55730-76-2 (R)-2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-3,6-dioxa-bicyclo[3.1.0]hexane 
• 55730-78-4 1,4-anhydro-3-deoxy-3-C-di(ethoxycarbonyl)methyl-D-altritol 
• 55730-74-0 1,4-anhydro-5,6-O-isopropylidene-2-O-methanesulfonyl-D-glucitol 
• 55730-79-5 [(2S,3S,4S)-2-((R)-1,2-Dihydroxy-ethyl)-4-hydroxy-tetrahydro-furan-3-yl]-acetic acid ethyl ester 
• 101069-41-4 1,4-anhydro-3-deoxy-3-C-(ethoxycarbonylmethyl)-5,6-O-isopropylidene-D-altritol 

Downstream Products

• 101069-35-6 (Z)-7-[(2S,3R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-furan-3-yl]-hept-5-enoic acid 
• 101069-30-1 methyl <2S-<2α(4R),3β(Z),4α>>-7-<4-(tert-butyldiphenylsilyloxy)-2-(2,2-dimethyl-1,3-dioxolan-4-yl)-tetrahydrofuran-3-yl>-5-heptenoate 
• 101069-38-9 [(2S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-2-formyl-tetrahydro-furan-3-yl]-acetic acid ethyl ester 
• 101069-32-3 (Z)-7-[(2S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-2-formyl-tetrahydro-furan-3-yl]-hept-5-enoic acid methyl ester 
• 101069-63-0 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3,5-dideoxy-3-C-(ethoxycarbonylmethyl)-5-C-(2-oxo-trans-heptylidene)-D-ribitol 
• 101069-31-2 (Z)-7-[(2S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-2-(1,2-dihydroxy-ethyl)-tetrahydro-furan-3-yl]-hept-5-enoic acid methyl ester 
• 101069-33-4 methyl <2S-<2α(1E),3β(Z),4β>>-7-<4-(tert-butyldiphenylsilyloxy)-tetrahydro-2-(3-oxo-1-octenyl)-furan-3-yl>-5-heptenoate 
• 101069-35-6 (Z)-7-[(2S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-furan-3-yl]-hept-5-enoic acid 
• 101069-34-5 O-tert-butyldiphenylsilyl-15S-11-oxaprostaglandin F₂α methyl ester 
• 101144-06-3 O-tert-butyldiphenylsilyl-15R-11-oxaprostaglandin F₂α methyl ester 
• 101069-30-1 methyl <2S-<2α(4R),3β(Z),4β>>-7-<4-(tert-butyldiphenylsilyloxy)-2-(2,2-dimethyl-1,3-dioxolan-4-yl)-tetrahydrofuran-3-yl>-5-heptenoate 
• 101069-29-8 1,4-anhydro-2-O-tert-butyldiphenylsilyl-3-deoxy-3-C-(formylmethyl)l-5,6-O-isopropylidene-D-allitol 
• 101069-37-8 [(2S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-2-(1,2-dihydroxy-ethyl)-tetrahydro-furan-3-yl]-acetic acid ethyl ester 
• 101069-29-8 [(2S,3R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-furan-3-yl]-acetaldehyde 

Relevant articles and documents

TOTAL SYNTHESIS OF 11-OXAPROSTAGLANDIN F2α AND F2β

1,4-Anhydro-D-glucitol has been used as a chiral template for the syntesis of 11-oxaprostaglandin F2α and F2β.Methodology was also developed to provide access to chiral, C-branched tetrahydrofuran derivatives.