1012886-58-6Relevant articles and documents
Nitrogen-Doped Carbon Enables Heterogeneous Asymmetric Insertion of Carbenoids into Amines Catalyzed by Rhodium Nanoparticles
Kobayashi, Shū,Masuda, Ryusuke,Yamashita, Yasuhiro,Yasukawa, Tomohiro
supporting information, p. 12786 - 12790 (2021/05/07)
Development of stable heterogeneous catalyst systems is a crucial subject to achieve sustainable society. Though metal nanoparticles are robust species, the study of asymmetric catalysis by them has been restricted because methods to activate metal nanopa
Electroreductive acylation of aromatic imines with acylimidazoles
Kise, Naoki,Morimoto, Shinji
, p. 1765 - 1771 (2008/09/18)
The intermolecular reductive coupling of aromatic imines with acylimidazoles was effected by electroreduction in the presence of chlorotrimethylsilane and gave α-amino-α-aryl ketones. This method was also effective for the synthesis of α-amino-α-aryl esters using methoxycarbonylimidazole as an electrophile.