101382-81-4

Basic information

• Product Name: tert-Butyl-((R)-2-methyl-3-oxiranyl-propoxy)-diphenyl-silane
• Synonyms: tert-Butyl-((R)-2-methyl-3-oxiranyl-propoxy)-diphenyl-silane
• CAS NO: 101382-81-4
• Molecular Weight: 354.565
• Mol File: 101382-81-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-Butyl-((R)-2-methyl-3-oxiranyl-propoxy)-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-((R)-2-methyl-3-oxiranyl-propoxy)-diphenyl-silane(101382-81-4)
• EPA Substance Registry System: tert-Butyl-((R)-2-methyl-3-oxiranyl-propoxy)-diphenyl-silane(101382-81-4)

Safety Data

• Hazardous Substances Data: 101382-81-4(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 56-86-0 L-glutamic acid 
• 32780-06-6 (5S)-5-(hydroxymethyl)-2-oxo-tetrahydrofuran 

Downstream Products

• 101382-87-0 2,2-Dimethyl-propionic acid (2S,4R,6R)-7-(tert-butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-2,6-dimethyl-heptyl ester 
• 101382-84-7 (3S,5S)-5-[(R)-3-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-propyl]-3-methyl-dihydro-furan-2-one 
• 101382-85-8 (2S,4R,6R)-7-(tert-Butyl-diphenyl-silanyloxy)-2,6-dimethyl-heptane-1,4-diol 
• 101382-94-9 tert-Butyl-[(R)-2-methyl-3-((S)-4-methyl-tetrahydro-furan-2-yl)-propoxy]-diphenyl-silane 
• 101382-88-1 (2S,6R)-7-tert-butyldiphenylsilyloxy-2,6-dimethyl-1-heptanol 
• 101382-86-9 2,2-Dimethyl-propionic acid (2S,4R,6R)-7-(tert-butyl-diphenyl-silanyloxy)-4-hydroxy-2,6-dimethyl-heptyl ester 
• 101382-89-2 (S)-5-[(R)-3-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-propyl]-3-methyl-5H-furan-2-one 
• 101382-83-6 (R)-5-[(R)-3-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-propyl]-dihydro-furan-2-one 
• 101382-82-5 (S)-5-[(R)-3-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-propyl]-3-phenylsulfanyl-dihydro-furan-2-one 

Relevant articles and documents

A Tactically Novel Alternative to Acyclic Stereoselection Based on the Concept of a Replicating Chiron - 1,5-C-Methyl Substitution

A synthetic sequence is described wherein a chiral butyrolactone is used as a template to control the stereochemistry of a C-methylation process on the corresponding enolate.A sequential two-carbon homologation and replication of the butyrolactone template allows a second stereocontrolled C-methylation.The ultimate outcome is a seven carbon acyclic chain with a predicable 1,5-substitution pattern of C-methyl groups with or without an intervening hydroxyl group.