101385-81-3

Basic information

• Product Name: (S)-3-Cyclohex-1-enyl-4-ethyl-2,2-dimethyl-[1,3,2]oxazasilolidine
• CAS NO: 101385-81-3
• Molecular Weight: 225.406
• Mol File: 101385-81-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-Cyclohex-1-enyl-4-ethyl-2,2-dimethyl-[1,3,2]oxazasilolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-Cyclohex-1-enyl-4-ethyl-2,2-dimethyl-[1,3,2]oxazasilolidine(101385-81-3)
• EPA Substance Registry System: (S)-3-Cyclohex-1-enyl-4-ethyl-2,2-dimethyl-[1,3,2]oxazasilolidine(101385-81-3)

Safety Data

• Hazardous Substances Data: 101385-81-3(Hazardous Substances Data)

Upstream product

• 75-78-5 dimethylsilicon dichloride 
• 3768-58-9 bis(dimethylamino)dimethylsilane 

Downstream Products

• 10407-33-7 methyl 3-(2-oxocyclohexyl)propionate 

Relevant articles and documents

REACTIVITE COMPAREE DES ISOMERES IMINE ET ENAMINE SILICIES: SYNTHESE ENANTIOSELECTIVE DE L'(OXO-2 CYCLOHEXYL)-3 PROPIONATE DE METHYLE

The isomerisation process between SiMe3-substituted enamines and imines (N-SiC-Si) is so slow that each isomer is able to react independently.The silicon-substituted (S)-phenylethylamine derivative adds to methyl acrylate and forms, upon hydrolysis, methyl (S)-3-(2-oxocyclohexyl)propane carboxylate.The tautomeric imine leads to the (R)-enantiomer.Surprisingly, in the presence of a Lewis acid, the ring-containing organosilicon-substituted derivatives show lower stereoselectivity than the corresponding tin compounds.