101414-51-1

Basic information

• Product Name: N-amino(p-nitrophenyl)dichlorosulfurane
• Synonyms: N-amino(p-nitrophenyl)dichlorosulfurane
• CAS NO: 101414-51-1
• Molecular Weight: 373.26
• Mol File: 101414-51-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-amino(p-nitrophenyl)dichlorosulfurane(CAS DataBase Reference)
• NIST Chemistry Reference: N-amino(p-nitrophenyl)dichlorosulfurane(101414-51-1)
• EPA Substance Registry System: N-amino(p-nitrophenyl)dichlorosulfurane(101414-51-1)

Safety Data

• Hazardous Substances Data: 101414-51-1(Hazardous Substances Data)

Upstream product

• 101414-54-4 ethyl N-(p-nitrophenylthio)benzenecarboximidate 
• 937-32-6 4-nitrobenzenesulfenyl chloride 
• 33243-83-3 N-chloro-benzimidic acid ethyl ester 

Downstream Products

• 101414-54-4 ethyl N-(p-nitrophenylthio)benzenecarboximidate 
• 1041-15-2 p-nitrophenyl p-nitrobenzenethiosulfonate 
• 13088-17-0 4-nitro-benzenesulfinyl chloride 
• 5333-86-8 ethyl benzimidate hydrochloride 
• 60199-42-0 p-nitrobenzoyl-(N-benzoyl)-iminosulfinyl chloride 

Relevant articles and documents

REACTION OF ARENESULFENYL CHLORIDES WITH N-CHLOROCARBONIMIDIC AND N-CHLOROBENZENECARBOXIMIDIC ESTERS. N-(ETHOXYCARBONYL)- AND N-BENZOYLARENESULFINIMIDOYL CHLORIDES

In the reaction of arenesulfonyl chlorides with diethyl N-chlorocarbonimidate or N-chlorobenzenecarboximidic esters at 20 deg C 1:1 adducts are formed, and they probably have the structure of tetracoordinated compounds of sulfur.The latter are also formed during the chlorination of N-(arylthio)carbonimidic or N-(arylthio)benzenecarboximidic esters.The obtained compounds are dechlorinated by the action of bases with the formation of N-(arylthio)carbonimidic or N-(arylthio)benzenecarboximidic esters.During acidolysis they split into arenesulfenyl chlorides and the salts of the corresponding carbonimidic and benzenecarboximidic esters.During thermolysis they eliminate alkyl chlorides and are converted into N-(ethoxycarbonyl)- or N-benzoylarenesulfinimidoyl chlorides.