1014621-33-0Relevant articles and documents
Unexpected formation of (dimethylaminomethylene)methylamide complexes from the reactions between metal chlorides and lithium dimethylamide
Zhang, Xin-Hao,Chen, Shu-Jian,Cai, Hu,Im, Hee-Jung,Chen, Tianniu,Yu, Xianghua,Chen, Xuetai,Lin, Zhenyang,Wu, Yun-Dong,Xue, Zi-Ling
, p. 1338 - 1341 (2008)
Reactions of MCl5 (M = Nb, Ta) with LiNMe2 have been found to yield M(NMe2)4(η2-MeNCH 2NMe2) (M = Nb, 2a; Ta, 2b) containing a chelating ligand (dimethylaminomethylene)methylamide, as confirmed by NMR spectroscopy, DFT calculations, and their reactivity studies.