101466-49-3

Basic information

• Product Name: 2-ethenyl-5-methoxyBenzaldehyde
• Synonyms: 2-ethenyl-5-methoxyBenzaldehyde
• CAS NO: 101466-49-3
• Molecular Weight: 162.188
• Mol File: 101466-49-3.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-ethenyl-5-methoxyBenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ethenyl-5-methoxyBenzaldehyde(101466-49-3)
• EPA Substance Registry System: 2-ethenyl-5-methoxyBenzaldehyde(101466-49-3)

Safety Data

• Hazardous Substances Data: 101466-49-3(Hazardous Substances Data)

Upstream product

• 7507-86-0 2-bromo-5-methoxy-benzaldehyde 
• 43192-31-0 2-bromo-4-methoxybenzaldehyde 
• 68-12-2 N,N-dimethyl-formamide 
• 153967-97-6 2-bromo-4-methoxy-1-vinylbenzene 
• 150192-39-5 2-Bromo-5-methoxybenzyl alcohol 
• 139557-96-3 (2-iodo-5-methoxyphenyl)methanol 
• 98015-08-8 2-<2-(1,3-dioxalanyl)>-4-methoxybenzaldehyde 
• 98015-07-7 2-Bromo-5-methoxybenzaldehyde ethylene glycol acetal 
• 101466-48-2 2-(5-Methoxy-2-vinyl-phenyl)-[1,3]dioxolane 

Downstream Products

• 101466-50-6 dimethyl 2,6-dimethyl-4-<(2-ethenyl-5-methoxy)phenyl>-1,4-dihydropyridine-3,5-dicarboxylate 
• 1446434-07-6 (R_s)-N-[(S)-1-(5-methoxy-2-vinylphenyl)but-3-en-1-yl]-2-methylpropane-2-sulfinamide 
• 1446433-98-2 (R_s,E)-N-(5-methoxy-2-vinylbenzylidene)-2-methylpropane-2-sulfinamide 
• 1620902-66-0 (2E)-3-(5-methoxy-2-vinylphenyl)prop-2-en-1-ol 
• 1620902-60-4 ethyl (2E)-3-(5-methoxy-2-vinylphenyl)prop-2-enoate 

Relevant articles and documents

Stereoselective Convergent Synthesis of Tetrahydro-5 H-benzo[c]fluorene via Nine-Membered Ring-Closing Metathesis and Transannular Acid-Mediated Cyclization/Nucleophilic Addition

The diene methyl ethers or acetates, constructed from the Li-Br exchange/addition reactions of 2-vinylbenzaldehydes and 2-(but-3-en-1-yl)bromoarenes followed by etherification or acetylation of the corresponding alcohols, smoothly underwent the ring-closi

Palladium-Catalyzed Tandem Hydrocarbonylative Lactamization and Cycloaddition Reaction for the Construction of Bridged Polycyclic Lactams

The intramolecular hydroaminocarbonylation of alkenes is a compelling tool to rapidly access lactam, a privileged motif ubiquitous in natural products, pharmaceuticals, and agrochemicals. However, selective carbonylation to bridged polycyclic lactams with a lactam nitrogen at a bridgehead position is less explored. We herein report a modular palladium-catalyzed approach to perform a tandem hydrocarbonylative lactamization/Diels-Alder cycloaddition reaction with 2-vinyl aryl aldimines, alkenes, and CO, which offers convenient access to furnish the bridged polycyclic lactams in high yields with high selectivities.

Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: Expedited construction of bridged polycyclic skeletons

A novel palladium-catalyzed highly selective hydrocarbonylative cycloaddition reaction with two different alkenes in the presence of CO enabled by a reactive directing-group is developed, which offers efficient and convenient access to lactone-containing bridged polycyclic compounds in high yield with high chemo- and stereoselectivities.