10152-89-3

Basic information

• Product Name: dimethyl 1,4,5,8-tetrahydro-1,4:5,8-diepoxynaphthalene-4a,8a-dicarboxylate
• CAS NO: 10152-89-3
• Molecular Formula: C₁₄H₁₄O₆
• Molecular Weight: 278.2574
• Mol File: 10152-89-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 366.5°C at 760 mmHg
• Flash Point: 162.1°C
• Density: 1.469g/cm³
• Vapor Pressure: 1.46E-05mmHg at 25°C
• Refractive Index: 1.595
• CAS DataBase Reference: dimethyl 1,4,5,8-tetrahydro-1,4:5,8-diepoxynaphthalene-4a,8a-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 1,4,5,8-tetrahydro-1,4:5,8-diepoxynaphthalene-4a,8a-dicarboxylate(10152-89-3)
• EPA Substance Registry System: dimethyl 1,4,5,8-tetrahydro-1,4:5,8-diepoxynaphthalene-4a,8a-dicarboxylate(10152-89-3)

Safety Data

• Hazardous Substances Data: 10152-89-3(Hazardous Substances Data)

Upstream product

• 110-00-9 furan 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 625-86-5 2,5-dimethylfuran 

Relevant articles and documents

Clay-catalyzed solventless addition reactions of furan with α,β- unsaturated carbonyl compounds

The reaction of furan with α,β-unsaturated carbonyl dienophiles catalyzed by K10 montmorillonite in the absence of organic solvents produces the corresponding Diels-Alder adducts and, in the case of methyl vinyl ketone, Michael-type products, under much milder conditions than the conventional protocols. The results are consistent with acid catalysis on the clay surface. Acrylates gave lower yields and/or decomposition products. The reaction can be extended to alkynic substrates such as DMAD to afford cycloadducts in good yields.