101639-86-5

Basic information

• Product Name: (1R,4R)-4-Hydroxy-1-methoxy-1,5-diphenyl-pentan-2-one
• Synonyms: (1R,4R)-4-Hydroxy-1-methoxy-1,5-diphenyl-pentan-2-one
• CAS NO: 101639-86-5
• Molecular Weight: 284.355
• Mol File: 101639-86-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,4R)-4-Hydroxy-1-methoxy-1,5-diphenyl-pentan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R)-4-Hydroxy-1-methoxy-1,5-diphenyl-pentan-2-one(101639-86-5)
• EPA Substance Registry System: (1R,4R)-4-Hydroxy-1-methoxy-1,5-diphenyl-pentan-2-one(101639-86-5)

Safety Data

• Hazardous Substances Data: 101639-86-5(Hazardous Substances Data)

Upstream product

• 96301-75-6 O-methylmandelaldehyde oxime 
• 20698-91-3 (R)-methyl mandelate 
• 611-71-2 (R)-Mandelic Acid 
• 72538-27-3 (-)-(R)-2-methoxy-2-phenylacetaldehyde 
• 32174-46-2 methyl (R)-(-)-2-methoxy-2-phenylacetate 
• 101639-84-3 5-benzyl-4,5-dihydro-3-(α-methoxy-benzyl)-isoxazole 
• 101693-97-4 O-methylmandelaldehyde oxime 
• 300-57-2 allylbenzene 
• 101639-84-3 5-Benzyl-3-((R)-methoxy-phenyl-methyl)-4,5-dihydro-isoxazole 
• 101639-84-3 (R)-5-Benzyl-3-((R)-methoxy-phenyl-methyl)-4,5-dihydro-isoxazole 

Downstream Products

• 101693-99-6 (4S,6R)-6-Benzyl-4-hydroxy-4-((R)-methoxy-phenyl-methyl)-[1,3]oxazinan-2-one 
• 101639-88-7 (4R,6S)-6-Benzyl-4-hydroxy-4-((R)-methoxy-phenyl-methyl)-[1,3]oxazinan-2-one 
• 101639-88-7 (S)-6-Benzyl-4-hydroxy-4-((R)-methoxy-phenyl-methyl)-[1,3]oxazinan-2-one 

Relevant articles and documents

The Use of Heterocyclic Chemistry in the Synthesis of Natural and Unnatural Products

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THE INTRAMOLECULAR NITRILE OXIDE-OLEFIN CYCLOADDITION ROUTE TO THE MAYTANSINOIDS

The macrocyclization of the olefinic nitrile oxide 24 to the ansa-macrolide skeleton 26, a model for a novel approach to the maytansinoids, is described.