1016650-79-5

Basic information

• Product Name: allyl 1-ethyl-2-oxocyclohexane-1-carboxylate
• Synonyms: allyl 1-ethyl-2-oxocyclohexane-1-carboxylate
• CAS NO: 1016650-79-5
• Molecular Weight: 210.273
• Mol File: 1016650-79-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: allyl 1-ethyl-2-oxocyclohexane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 1-ethyl-2-oxocyclohexane-1-carboxylate(1016650-79-5)
• EPA Substance Registry System: allyl 1-ethyl-2-oxocyclohexane-1-carboxylate(1016650-79-5)

Safety Data

• Hazardous Substances Data: 1016650-79-5(Hazardous Substances Data)

Upstream product

• 91906-66-0 pimelic acid diallyl ester 
• 75-03-6 ethyl iodide 
• 111-16-0 heptanedioic acid 
• 5453-93-0 allyl 2-oxocyclohexane-1-carboxylate 

Downstream Products

• 4423-94-3 (R)-(-)-2-ethylcyclohexan-1-one 
• 75599-12-1 (S)-(+)-2-ethylcyclohexan-1-one 
• 812639-08-0 (S)-2-allyl-2-ethylcyclohexanone 
• 58711-05-0 (±)-2-allyl-2-ethylcyclohexanone 
• 1221169-03-4 C₁₉H₂₂N₂O₂ 
• 1221168-69-9 C₂₁H₂₄N₂O 
• 1221168-71-3 C₂₁H₂₄N₂O 

Relevant articles and documents

Biocatalytic Conversion of Cyclic Ketones Bearing α-Quaternary Stereocenters into Lactones in an Enantioselective Radical Approach to Medium-Sized Carbocycles

Cyclic ketones bearing α-quaternary stereocenters underwent efficient kinetic resolution using cyclohexanone monooxygenase (CHMO) from Acinetobacter calcoaceticus. Lactones possessing tetrasubstituted stereocenters were obtained with high enantioselectivi

Homogeneous pd-catalyzed enantioselective decarboxylative protonation

General homogeneous conditions for the palladium-catalyzed synthesis of carbonyl compounds with tertiary carbon stereocenters at the a-position are reported. The highly reactive catalyst tolerates a variety of substrate substitution and functionality, and generates enantioenriched cyclic ketones from racemic allyl ss-ketoester starting materials.