1017235-66-3

Basic information

• Product Name: Co(P(CH₃)3)3(SP(C₆H₅)2C₆H₄)
• CAS NO: 1017235-66-3
• Molecular Weight: 580.577
• Mol File: 1017235-66-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Co(P(CH₃)3)3(SP(C₆H₅)2C₆H₄)(CAS DataBase Reference)
• NIST Chemistry Reference: Co(P(CH₃)3)3(SP(C₆H₅)2C₆H₄)(1017235-66-3)
• EPA Substance Registry System: Co(P(CH₃)3)3(SP(C₆H₅)2C₆H₄)(1017235-66-3)

Safety Data

• Hazardous Substances Data: 1017235-66-3(Hazardous Substances Data)

Upstream product

• 210900-54-2 mer-hydrido-(3,5-di-tert-butyl-2-oxobenzoyl)tris(trimethylphosphane)cobalt(III) 
• 119327-17-2 (2-mercaptophenyl)diphenylphosphine 
• 210900-66-6 mer-hydrido(2-oxo-naphthalene-formyl)tris(trimethylphosphine)cobalt(III) 
• 210900-98-4 mer-hydrido-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)tris(trimethylphosphane)cobalt(III) 
• 210900-91-7 mer-hydrido-(1-carbonyl-2-oxo-cyclohexenediyl)tris(trimethylphosphane)cobalt(III) 

Relevant articles and documents

Reaction of acyl(hydrido)cobalt(III) complexes with (2-diphenylphosphanyl)thiophenol and the influence of chelating ligands containing hard/soft donor atoms on the stability of cobalt complexes

The reaction of acyl(hydrido)cobalt(III) complexes CoIII(O∩C{double bond, long}O)(H)(PMe3)3 (1-5) with (2-diphenylphosphanyl)thiophenol afforded four types of complexes CoIII(O∩C{double bond, long}O)(P∩S)(PMe3)2 (6-7), CoIII(O∩C{double bond, long}O)(O∩OHC)(PMe3)2 (11-15), CoI(P∩S)(PMe3)3 (16), and CoII(P∩S)2(PMe3) (17). A mechanism for the formation of these complexes is proposed. The influences of chelating ligands containing hard/soft donor atoms on the stability of the cobalt complexes in different oxidation states are discussed with respect to the HSAB concept.