1017572-70-1

Basic information

• Product Name: (Z)-4-methoxy-N-(1-phenyl-3-(trimethylsilyl)prop-2-ynylidene)aniline
• Synonyms: (Z)-4-methoxy-N-(1-phenyl-3-(trimethylsilyl)prop-2-ynylidene)aniline
• CAS NO: 1017572-70-1
• Molecular Weight: 307.467
• Mol File: 1017572-70-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-4-methoxy-N-(1-phenyl-3-(trimethylsilyl)prop-2-ynylidene)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4-methoxy-N-(1-phenyl-3-(trimethylsilyl)prop-2-ynylidene)aniline(1017572-70-1)
• EPA Substance Registry System: (Z)-4-methoxy-N-(1-phenyl-3-(trimethylsilyl)prop-2-ynylidene)aniline(1017572-70-1)

Safety Data

• Hazardous Substances Data: 1017572-70-1(Hazardous Substances Data)

Upstream product

• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 53210-13-2 copper(I) (trimethylsilyl)acetylide 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 34918-74-6 N-(4-methoxyphenyl)benzimidoyl chloride 
• 1066-54-2 trimethylsilylacetylene 

Downstream Products

• 4789-73-5 2-phenyl-6-methoxyquinoline 

Relevant articles and documents

Synthesis of substituted pyridines and quinolines

A variety of N-vinyl and N-aryl amides were converted to the corresponding pyridine and quinoline derivatives, respectively. Amide activation and nucleophilic addition of copper(I) (trimethylsilyl)acetylide efficiently provided the desired alkynyl imines. Ruthenium-catalyzed protodesilylation and cycloisomerization of these imines gave the corresponding azaheterocycles. Georg Thieme Verlag Stuttgart.

Metal-free synthesis of alkynyl imines using an oxophosphonium-mediated approach at ambient temperatures

A metal-free approach was developed for the mild synthesis of N-aryl α-alkynyl imines from corresponding amide precursors for the first time. The electronic effects of substrates and the reaction mechanisms were investigated and discussed. This newly deve