1018069-38-9

Basic information

• Product Name: (E)-2-bromo-4-styrylphenol
• Synonyms: (E)-2-bromo-4-styrylphenol
• CAS NO: 1018069-38-9
• Molecular Weight: 275.145
• Mol File: 1018069-38-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-bromo-4-styrylphenol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-bromo-4-styrylphenol(1018069-38-9)
• EPA Substance Registry System: (E)-2-bromo-4-styrylphenol(1018069-38-9)

Safety Data

• Hazardous Substances Data: 1018069-38-9(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 1252036-60-4 3-bromo-4-hydroxybenzenediazonium tetrafluoroborate 

Downstream Products

• 17377-95-6 benzyl(4-methoxyphenyl)amine 
• 1613-90-7 4-methoxy-N-[(E)-phenylmethylidene]aniline 

Relevant articles and documents

Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via C=C Bond Cleavage

C=C bond breaking to access the C=N bond remains an underdeveloped area. A new protocol for C=C bond cleavage of alkenes under nonoxidative conditions to produce imines via an iron-catalyzed nitrene transfer reaction of 4-hydroxystilbenes with aryl azides is reported. The success of various sequential one-pot reactions reveals that the good compatibility of this method makes it very attractive for synthetic applications. On the basis of experimental observations, a plausible reaction mechanism is also proposed.