102059-02-9

Basic information

• Product Name: Benzene, 1,2-bis(phenylsulfonyl)-
• CAS NO: 102059-02-9
• Molecular Formula: C18H14O4S2
• Molecular Weight: 358.439
• Mol File: 102059-02-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2-bis(phenylsulfonyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2-bis(phenylsulfonyl)-(102059-02-9)
• EPA Substance Registry System: Benzene, 1,2-bis(phenylsulfonyl)-(102059-02-9)

Safety Data

• Hazardous Substances Data: 102059-02-9(Hazardous Substances Data)

Upstream product

• 3379-36-0 1,2-bis(phenylthio)benzene 
• 21691-17-8 benzene-1,2-disulfonyl diazide 
• 71-43-2 benzene 
• 1192-40-1 copper(I) thiophenolate 
• 930-69-8 sodium thiophenolate 
• 615-41-8 2-iodochlorobenzene 
• 102059-00-7 1,2-bis(benzenethio)-1,4-cyclohexadiene 
• 18893-63-5 (E)-1,2-bis(phenylsulfanyl)ethylene 
• 102059-03-0 ortho-phenylsulfonyl phenyl sulfoxide 
• 127-63-9 diphenyl sulphone 
• 95-50-1 1,2-dichloro-benzene 

Downstream Products

• 23038-47-3 1-benzenesulfonyl-2-methoxy-benzene 
• 1016-05-3 dibenzothiophene sulfone 
• 127-63-9 diphenyl sulphone 
• 64939-42-0 1-(phenylsulphonyl)-2-(phenylthio)benzene 
• 52914-17-7 (2-benzenesulfonyl-phenyl)-phenyl-amine 
• 101431-66-7 1-benzenesulfonyl-2-tert-butoxy-benzene 
• 101584-74-1 1-(2-benzenesulfonyl-phenyl)-piperidine 
• 101431-39-4 (2-butyl-phenyl)-phenyl sulfone 

Relevant articles and documents

Regiospecific Cleavage of S-N Bonds in Sulfonyl Azides: Sulfonyl Donors

Sulfonyl azides have been widely used as sulfonamido, diazo, and azido donors, as well as all-nitrogen 1,3-dipoles donors in synthetic chemistry. Here, the sulfonyl azides were used as efficient sulfonyl donors, which is very unusual. Trifluoromethanesulfonic acid-induced formation of the sulfonyl cation reactive species from sulfonyl azides was developed and used for the first time to couple various inactivated arenes to prepare sulfones at ambient temperature.

SYNTHESIS AND DIELS-ALDER REACTIONS OF 2,3-BIS(BENZENETHIO)-1,3-BUTADIENE

Two different routes to the preparation of 2,3-bis(benzenethio)-1,3-butadiene (1) are reported.Diene 1 is shown to react with maleic anhydride, (E)-1,2-bis(benzenesulfonyl)ethylene and 4-phenyl-1,2,4-triazoline-3,5-dione to give the respective Diels-Alder