102118-94-5Relevant articles and documents
Direct Synthesis of α-Allenols from TMS-Protected Alkynes and Aldehydes Mediated by Tetrabutylammonium Fluoride
Huang, Xiaojun,Bugarin, Alejandro
, p. 12696 - 12700 (2016)
A unique chemoselective synthesis of α-allenic alcohols is presented. Tetrabutylammonium fluoride (TBAF) mediated this transformation under mild reaction conditions. A range of functional groups is well-tolerated in this reaction, while affording adducts
Allene/haloolefin electrocyclic reactions: A new route to stable triarylmethyl radicals
Porter, Ned A.,Hogenkamp, Derk J.,Khouri, Farid F.
, p. 2402 - 2407 (2007/10/02)
Electrocyclization of allene 1,1-diphenyl-3-[2-(2-bromoethenyl)phenyl]propadiene (5), followed by one-electron reduction with elemental mercury, gives β-naphthyldiphenylmethyl radical 6 in good yield. In the absence of mercury, the only product isolated i
PALLADIUM COMPLEX CATALYSED REACTION OF DIPHENYLKETENE WITH TERMINAL ACETYLENES GIVING DISUBSTITUTED ACETYLENES
Mitsudo, Take-aki,Kadokura, Mamoru,Watanabe, Yoshihisa
, p. 3697 - 3698 (2007/10/02)
The reaction of diphenylketene with terminal acetylenes catalyzed by tetrakis(triphenylphosphine)palladium gave disubstituted acetylenes in high yields.