1021297-63-1

Basic information

• Product Name: (R)-4-benzyl-3-((2S,3R,4S,5R)-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-3-hydroxy-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one
• Synonyms: (R)-4-benzyl-3-((2S,3R,4S,5R)-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-3-hydroxy-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one
• CAS NO: 1021297-63-1
• Molecular Weight: 759.985
• Mol File: 1021297-63-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-benzyl-3-((2S,3R,4S,5R)-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-3-hydroxy-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-benzyl-3-((2S,3R,4S,5R)-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-3-hydroxy-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one(1021297-63-1)
• EPA Substance Registry System: (R)-4-benzyl-3-((2S,3R,4S,5R)-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-3-hydroxy-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one(1021297-63-1)

Safety Data

• Hazardous Substances Data: 1021297-63-1(Hazardous Substances Data)

Upstream product

• 875576-42-4 (2R,3R)-2,3-bis(benzyloxy)-4,4-bis(ethylthio)butanal 

Downstream Products

• 1021297-64-2 (R)-4-benzyl-3-((2S,3R,4S,5R)-3-acetoxy-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one 
• 1021297-67-5 (R)-4-benzyl-3-((2S,3R,4S,5R)-3-levulinoxy-4,5-bis(benzyloxy)-6,6-bis(ethylthio)-2-(4-methoxybenzyloxy)hexanoyl)oxazolidin-2-one 

Relevant articles and documents

De novo sythesis of a D-galacturonic acid thioglycoside as key to the total synthesis of a glycosphingolipid from

A concise synthesis of a differentially protected D-galacturonic acid (D-GalA) thioglycoside and the construction of a potent immunomodulating glycosphingolipid are described. The key steps of the synthesis are an Evans aldol reaction between a C4 aldehyde and a PMB-protected glycolyloxazolidinone as well as a tandem-PMB-deprotection/cyclization to thioglycosides. The key glycosylation step is optimized by varying the anomeric leaving group, the activating agent, and the solvent system.