102147-31-9

Basic information

• Product Name: Propanoic acid, 2,2-dimethyl-, 2-cyclohexen-1-yl ester
• CAS NO: 102147-31-9
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol File: 102147-31-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propanoic acid, 2,2-dimethyl-, 2-cyclohexen-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanoic acid, 2,2-dimethyl-, 2-cyclohexen-1-yl ester(102147-31-9)
• EPA Substance Registry System: Propanoic acid, 2,2-dimethyl-, 2-cyclohexen-1-yl ester(102147-31-9)

Safety Data

• Hazardous Substances Data: 102147-31-9(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 75-98-9 Trimethylacetic acid 

Downstream Products

• 3983-07-1 3-n-butylcyclohexene 
• 958264-92-1 C₁₉H₃₆O₂Si 
• 345218-57-7 C₁₈H₁₉N 
• 1184930-47-9 2-((S)-((S)-cyclohex-2-enyl)(phenyl)methyl)pyridine 
• 1184930-49-1 2-((S)-((S)-cyclohex-2-enyl)(3,5-dimethoxyphenyl)methyl)pyridine 
• 1184930-51-5 2-((S)-((S)-cyclohex-2-enyl)(naphthalen-2-yl)methyl)pyridine 
• 1184930-52-6 2-((S)-((S)-cyclohex-2-enyl)(thiophen-3-yl)methyl)pyridine 
• 1184930-50-4 2-((S)-(4-chlorophenyl)((S)-cyclohex-2-enyl)methyl)pyridine 

Relevant articles and documents

Allylic Carboxylations and Lactonization Using Benzoquinone and Hydrogen Peroxide or tert-Butyl Hydroperoxide as Oxidants

Two new systems have been developed for catalytic carboxylation of alkenes.Both use palladium(II) as catalyst and benzoquinone as cocatalyst.In the first hydrogen peroxide was used as oxidant in acetic acid solution.Alkenes such as cyclohexene and 5-decene were converted cleanly to allylic acetates, but with 1-decene mainly the methyl ketone was formed.A diene such as 1,3-cyclohexadiene gave the diacetate while cis-1,2-divinylcyclohexane gave the cyclized monoacetate.In the second system, tert-butyl hydroperoxide was used as oxidant, permitting a wider choice of solvents and nucleophiles.Intramolecular reaction to lactones was possible in addition to allylic addition of acids such as benzoic, pivalic, and (S)-O-acetylmandelic acid.